▪ Abstract This paper describes the reproducing kernel Hilbert space (RKHS) method for
constructing accurate, smooth, and efficient global potential energy surface (PES) …

This review deals with the relation between intermolecular potentials and the spectra of van
der Waals molecules. Intermolecular potentials cannot be measured directly, but the …

Earning tenure at an academic institution and running a steeplechase race successfully
have a lot in common. Both require extensive training before the event begins, both involve …

This paper describes a procedure for optimal rounding of parameters determined from a
linear or nonlinear least-squres fit in order to minimize the number of digits which must be …

The intermolecular potential energy surface of the He–CO complex including the CO bond
length dependence has been calculated using symmetry-adapted perturbation theory …

A new density functional theory (DFT) for calculations of van der Waals (vdW) complexes is
presented. In this scheme, a long-range-corrected exchange-correlation functional is …

Helium is the only substance that has been observed on macroscopic scale to form the
fourth state of matter, the superfluid state. However, until recently superfluid helium had not …

A flexible new analytical representation for the internuclear potential energy of a diatomic
molecule is proposed and tested. The new model may be thought of as a generalization of …

The infrared spectrum of the HeC02 van der Waals molecule is recorded in the region of the
CO2 V3 asymmetric stretch via direct absorption of a tunable Pb-salt diode laser. HeC02 is …

Infrared spectra of He N–CO complexes with N up to about 20 have been observed in the
2145 cm− 1 region of the C–O stretch vibration using a tunable diode laser spectrometer to …