Microstructural and dynamical heterogeneities in ionic liquids

YL Wang, B Li, S Sarman, F Mocci, ZY Lu… - Chemical …, 2020 - ACS Publications
Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied
molecular symmetry and charge delocalization. The versatility in combining varied cation …

The interactions between polar solvents (methanol, acetonitrile, dimethylsulfoxide) and the ionic liquid 1-ethyl-3-methylimidazolium bis (fluorosulfonyl) imide

Y Zhou, S Gong, X Xu, Z Yu, J Kiefer, Z Wang - Journal of Molecular Liquids, 2020 - Elsevier
In practical applications, ionic liquids (ILs) are usually used in mixtures with polar solvents to
reduce the cost of neat ILs and to manipulate their physicochemical properties. To apply …

[HTML][HTML] EMIMBF4 in ternary liquid mixtures of water, dimethyl sulfoxide and acetonitrile as “tri-solvent-in-salt” electrolytes for high-performance supercapacitors …

X Lu, JM Vicent-Luna, S Calero… - Energy Storage …, 2021 - Elsevier
For many years, the performance of Li-ion batteries (LIBs) and supercapacitors (SCs) has
relied mainly on two factors,(1) the optimization of electrodes composition and/or structure …

Ionic liquids with fluorine-containing anions as a new class of functional materials: features of the synthesis, physicochemical properties, and use

SA Prikhod'ko, AY Shabalin, MM Shmakov… - Russian Chemical …, 2020 - Springer
The results obtained by the authors and literature data on the methods of preparation,
properties, and the use of ionic liquids with fluorine-containing anions are reviewed. The …

[HTML][HTML] Understanding the role of temperature in structural changes of choline chloride/glycols deep eutectic solvents

F Gabriele, M Chiarini, R Germani, N Spreti - Journal of Molecular Liquids, 2023 - Elsevier
Deep eutectic solvents (DESs) represent a new “green” alternative to classic organic
solvents; however, their high viscosity often limits their utilization. The physicochemical …

Structural Features of the [C4mim][Cl] Ionic Liquid and Its Mixtures with Water: Insight from a 1H NMR Experimental and QM/MD Study

D Lengvinaitė, S Kvedaraviciute… - The Journal of …, 2021 - ACS Publications
The 1H NMR chemical shift of water exhibits non-monotonic dependence on the
composition of an aqueous mixture of 1-butyl-3-methylimidazolium chloride,[C4mim][Cl] …

Confined water in imidazolium based ionic liquids: a supramolecular guest@ host complex case

M Zanatta, AL Girard, G Marin, G Ebeling… - Physical Chemistry …, 2016 - pubs.rsc.org
It is well known that the macroscopic physico-chemical properties of ionic liquids (ILs) are
influenced by the presence of water that strongly interferes with the supramolecular …

Balancing the Co‐Solvent Content in High Entropy Aqueous Electrolytes to Obtain 2.2 V Symmetric Supercapacitors

L González‐Aguilera, JM Vicent‐Luna… - Advanced Functional …, 2024 - Wiley Online Library
The energy storage capability of supercapacitors (SCs) strongly depend on the operating
cell voltage of the electrolytes of choice. In this regard, the inherent distinct electrochemical …

Validation of structural grounds for anomalous molecular mobility in ionic liquid glasses

MY Ivanov, SA Prikhod'ko, OD Bakulina, AS Kiryutin… - Molecules, 2021 - mdpi.com
Ionic liquid (IL) glasses have recently drawn much interest as unusual media with unique
physicochemical properties. In particular, anomalous suppression of molecular mobility in …

Local structure in terms of nearest-neighbor approach in 1-butyl-3-methylimidazolium-based ionic liquids: MD simulations

BA Marekha, VA Koverga, E Chesneau… - The Journal of …, 2016 - ACS Publications
Description of the local microscopic structure in ionic liquids (ILs) is a prerequisite to obtain a
comprehensive understanding of the influence of the nature of ions on the properties of ILs …