Surface-catalyzed C–C covalent coupling strategies toward the synthesis of low-dimensional carbon-based nanostructures

Q Fan, JM Gottfried, J Zhu - Accounts of chemical research, 2015 - ACS Publications
Conspectus Carbon-based nanostructures have attracted tremendous interest because of
their versatile and tunable properties, which depend on the bonding type of the constituting …

Surface-activated coupling reactions confined on a surface

L Dong, PN Liu, N Lin - Accounts of chemical research, 2015 - ACS Publications
Conspectus Chemical reactions may take place in a pure phase of gas or liquid or at the
interface of two phases (gas–solid or liquid–solid). Recently, the emerging field of “surface …

Substrate-independent growth of atomically precise chiral graphene nanoribbons

DG de Oteyza, A García-Lekue, M Vilas-Varela… - ACS …, 2016 - ACS Publications
Contributing to the need for new graphene nanoribbon (GNR) structures that can be
synthesized with atomic precision, we have designed a reactant that renders chiral (3, 1) …

On-surface Ullmann coupling: the influence of kinetic reaction parameters on the morphology and quality of covalent networks

J Eichhorn, D Nieckarz, O Ochs, D Samanta… - ACS …, 2014 - ACS Publications
On-surface Ullmann coupling is a versatile and appropriate approach for the bottom-up
fabrication of covalent organic nanostructures. In two-dimensional networks, however, the …

Dehalogenative homocoupling of terminal alkynyl bromides on Au (111): incorporation of acetylenic scaffolding into surface nanostructures

Q Sun, L Cai, H Ma, C Yuan, W Xu - ACS nano, 2016 - ACS Publications
On-surface C–C coupling reactions of molecular precursors with alkynyl functional groups
demonstrate great potential for the controllable fabrication of low-dimensional carbon …

Lattice-directed formation of covalent and organometallic molecular wires by terminal alkynes on Ag surfaces

J Liu, Q Chen, L Xiao, J Shang, X Zhou, Y Zhang… - ACS …, 2015 - ACS Publications
Surface reactions of 2, 5-diethynyl-1, 4-bis (phenylethynyl) benzene on Ag (111), Ag (110),
and Ag (100) were systematically explored and scrutinized by scanning tunneling …

Concentration-directed polymorphic surface covalent organic frameworks: Rhombus, parallelogram, and kagome

YP Mo, XH Liu, D Wang - ACS nano, 2017 - ACS Publications
Polymorphic single-layered covalent organic frameworks (sCOFs) via on-surface synthesis
have been investigated by employing the tetradentate monomer 1, 3, 6, 8-tetrakis (p …

On-surface azide–alkyne cycloaddition on Au (111)

O Diaz Arado, H Monig, H Wagner, JH Franke… - ACS …, 2013 - ACS Publications
We present [3+ 2] cycloaddition reactions between azides and alkynes on a Au (111)
surface at room temperature and under ultrahigh vacuum conditions. High-resolution …

On-surface synthesis of two-dimensional covalent organic structures versus halogen-bonded self-assembly: Competing formation of organic nanoarchitectures

D Peyrot, F Silly - ACS nano, 2016 - ACS Publications
The competition between the on-surface synthesis of covalent nanoarchitectures and the
self-assembly of star-shaped 1, 3, 5-Tris (4-iodophenyl) benzene molecules on Au (111) in …

Effect of metal surfaces in on-surface Glaser coupling

HY Gao, JH Franke, H Wagner, D Zhong… - The Journal of …, 2013 - ACS Publications
The homocoupling of alkynes at metal surfaces, which was disclosed recently, is a
promising reaction for efficient construction of conjugated nanostructures at metal surfaces …