Influence of Donnan and dielectric exclusion on ion sorption in sulfonated polysulfones
Abstract The Donnan–Manning model accurately describes the thermodynamic properties
(eg, ion sorption) of many charged polymers equilibrated with aqueous electrolytes, such as …
(eg, ion sorption) of many charged polymers equilibrated with aqueous electrolytes, such as …
[HTML][HTML] Contributions to Ionic Activity Coefficients: A Review and Comparison of Equations of State with Molecular Simulations
Advanced equations of state for electrolyte solutions (e-EoS) consist of many contributions
stemming from different intermolecular forces, eg repulsion, dispersion, hydrogen bonding …
stemming from different intermolecular forces, eg repulsion, dispersion, hydrogen bonding …
The Connection between the Debye and Güntelberg Charging Processes and the Importance of Relative Permittivity: The Ionic Cloud Charging Process
The Debye and Güntelberg Charging Processes are essential tools for deriving electrolyte
solutions' activity coefficient models. The Debye–Hückel, Born, and Mean Spherical …
solutions' activity coefficient models. The Debye–Hückel, Born, and Mean Spherical …
[HTML][HTML] Behavior of the aqueous sodium chloride solutions from molecular simulations and theories
Molecular simulations and theories are important tools for studying electrolyte solutions. In
this work, molecular dynamics simulations with one of the most widely used force field …
this work, molecular dynamics simulations with one of the most widely used force field …
[HTML][HTML] Theoretical considerations on single and mixed solvent electrolyte solutions
In this paper, theoretical considerations on electrolyte thermodynamic models are discussed
for single and mixed solvent solutions. A literature review has revealed that for many …
for single and mixed solvent solutions. A literature review has revealed that for many …
[HTML][HTML] Resurrection of Hückel's idea: Decoupling ion–ion and ion–water terms in activity coefficients via the state-dependent dielectric constant
Although Hückel proposed the basic idea of using a concentration dependent dielectric
constant, ϵ (c), to compute the activity coefficients of ions in electrolytes in 1925 (Hückel …
constant, ϵ (c), to compute the activity coefficients of ions in electrolytes in 1925 (Hückel …
Application of the Born Model to Describe Salt Partitioning in Hydrated Polymers
The classic Born model can be used to predict salt partitioning properties observed in
hydrated polymers, but there are often significant quantitative discrepancies between these …
hydrated polymers, but there are often significant quantitative discrepancies between these …
Permittivity Modeling in Electrolyte PC-SAFT
Accurately modeling the thermodynamic properties of electrolyte systems is key to designing
decarbonized energy and chemical processes. For this purpose, a promising model class …
decarbonized energy and chemical processes. For this purpose, a promising model class …
[HTML][HTML] Improving the Born equation: Origin of the Born radius and introducing dielectric saturation effects
The Born equation is a seminal model to study the solvation process of ions in solution,
devised originally for ions at infinite dilution. Diverse modifications have been proposed in …
devised originally for ions at infinite dilution. Diverse modifications have been proposed in …
[HTML][HTML] Permittivity Characterization of Conductive and Corrosive LiBr Water Solutions, Method Validation up to 9 GHz Using a Low-Cost SMA Probe
In this article, we present a method for extracting the complex permittivity of high-conductivity
solutions up to 9 GHz. Microwave measurements were performed using a low-cost SMA …
solutions up to 9 GHz. Microwave measurements were performed using a low-cost SMA …