Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …

Chiral amines are key structural motifs present in a wide variety of natural products, drugs,
and other biologically active compounds. During the past decade, significant advances have …

Since the development of BisP* ligand by Imamoto, P-stereogenic phosphines bearing a
bulky tert-butyl group and a smaller alkyl group have demonstrated extraordinary proficiency …

Chiral phosphorus ligands have played a crucial role for the recent advances in asymmetric
catalysis. This review summarizes chiral phosphorus ligands developed from the Laboratory …

Catalytic asymmetric hydrogenation of enamido phosphorus derivatives is one of the most
efficient methods for the construction of chiral amino phosphorus products, among which the …

The catalytic asymmetric hydrogenation of prochiral olefins is one of the most widely studied
and utilized transformations in asymmetric synthesis. This straightforward, atom economical …

L-threonine transaldolase (PsLTTA) could asymmetric synthesize β-hydroxy-α-amino acids
(HAAs) with excellent stereoselectivity, while the poor yield limited its further application …

Abstract l‐Threonine aldolase from Actinocorallia herbida (AhLTA) is an ideal catalyst for
producing l‐threo‐4‐methylsulfonylphenylserine [(2S, 3R)‐1 b], a key chiral precursor for …

Ketoreductases have shown considerable potential as biocatalysts in the asymmetric
synthesis of chiral alcohols. However, compared to the widely studied ketoreductases for …

A highly regio‐and enantioselective hydrogenation of challenging tetrasubstituted allenyl
sulfones has been developed, affording chiral allylic sulfones in good yields with excellent …