Storing energy with molecular photoisomers

Z Wang, P Erhart, T Li, ZY Zhang, D Sampedro, Z Hu… - Joule, 2021 - cell.com
Some molecular photoisomers can be isomerized to a metastable high-energy state by
exposure to light. These molecules can then be thermally or catalytically converted back to …

Visible‐light‐activated molecular switches

D Bléger, S Hecht - Angewandte Chemie International Edition, 2015 - Wiley Online Library
The ability to influence key properties of molecular systems by using light holds much
promise for the fields of materials science and life sciences. The cornerstone of such …

Smart photochromic materials triggered with visible light

AL Leistner, ZL Pianowski - European Journal of Organic …, 2022 - Wiley Online Library
Molecular photoswitches reversibly convert the energy of light into a variety of structural
changes at the molecular level. They can be integrated into smart materials with broad …

Excited state non-adiabatic dynamics of large photoswitchable molecules using a chemically transferable machine learning potential

S Axelrod, E Shakhnovich… - Nature …, 2022 - nature.com
Light-induced chemical processes are ubiquitous in nature and have widespread
technological applications. For example, photoisomerization can allow a drug with a photo …

Functionalized cellulose nanocrystals as active reinforcements for light-actuated 3D-printed structures

LAE Müller, A Zingg, A Arcifa, T Zimmermann… - ACS …, 2022 - ACS Publications
Conventional manufacturing techniques allow the production of photoresponsive cellulose
nanocrystals (CNC)-based composites that can reversibly modify their optical, mechanical …

Orange-Light-Induced Photochemistry Gated by pH and Confined Environments

D Kodura, LL Rodrigues, SL Walden… - Journal of the …, 2022 - ACS Publications
We introduce a new photochemically active compound, ie, pyridinepyrene (PyPy), entailing
a pH-active moiety that effects a significant halochromic shift into orange-light (λ= 590 nm) …

(Hetero) arylazo-1, 2, 3-triazoles:“Clicked” photoswitches for versatile functionalization and electronic decoupling

D Fang, ZY Zhang, Z Shangguan, Y He… - Journal of the …, 2021 - ACS Publications
The development of light-responsive chemical systems often relies on the rational design
and suitable incorporation of molecular photoswitches such as azobenzenes. Linking a …

Advances in direct metal-catalyzed functionalization of azobenzenes

THL Nguyen, N Gigant, D Joseph - ACS Catalysis, 2018 - ACS Publications
Azobenzenes are a unique class of compounds that originally aroused interest because of
their exceptional photochromic properties. Selective reactions allowing the preparation of …

Prospects of improving molecular solar energy storage of the norbornadiene/Quadricyclane system through bridgehead modifications

AE Hillers-Bendtsen… - The Journal of …, 2022 - ACS Publications
We have investigated novel bicyclic diene molecular solar thermal energy storage systems
that presently are the ones with the highest predicted energy density. Using a variety of …

Supramolecular hierarchy among halogen and hydrogen bond donors in light-induced surface patterning

M Saccone, V Dichiarante, A Forni… - Journal of Materials …, 2015 - pubs.rsc.org
Halogen bonding, a noncovalent interaction possessing several unique features compared
to the more familiar hydrogen bonding, is emerging as a powerful tool in functional materials …