The simple and efficient conversion of carbonyl compounds into functionalized alkanes via
deoxygenation is highly enabling in chemical synthesis. This Review covers the recent …

Electrocarboxylation of organic halides is one of the most investigated electrochemical
approaches for converting thermodynamically inert carbon dioxide (CO2) into value-added …

O-Phosphination of α-dicarbonyls via sequential in situ formation of a Kukhtin–Ramirez
adduct and a P (NMe2) 3-catalyzed process has been exploited for the synthesis of α …

In this report, a P (NMe2) 3-mediated reductive intramolecular annulation reaction has been
developed with benzoyl formates bearing a trisubstituted alkene unit. It provides a facile …

Herein, we disclose a fascinating highly stereoselective P (NMe2) 3 mediated intramolecular
deoxygenative umpolung cascade Michael addition-initiated cyclopropanation with a …

A deoxygenative geminal fluorosulfonimidation of 1, 2-diketones was achieved for the
synthesis of tetrasubstituted α-fluoroamines under mild conditions. In this study, a transition …

An unprecedented reductive [2+ 1] annulation of α-keto esters with alkynones mediated by P
(NMe2) 3 is described. Although this nonmetal cyclopropenation is a nucleophilic process …

Allyl 2-diazo-2-phenylacetates are shown to react with trimethylsilyl thioethers in the
presence of rhodium (II) catalysts to generate α-allyl-α-thio silyl esters. The transformation …

Simultaneous multiple displacements of organic molecules can lead to a large structural
reconstruction with increased complexity that would be difficult to access otherwise …

Our group has recently developed an α-fluoroamine synthesis using dioxaphospholenes
derived from various 1, 2-diketones and the dealkylation-resistant phosphoramidite as …