Sulfoxonium ylides: simple compounds with chameleonic reactivity

GD Bisag, S Ruggieri, M Fochi… - Organic & Biomolecular …, 2020 - pubs.rsc.org
Sulfur ylides first disclosed in 1930 started to gain more attention in the 1960s, thanks mainly
to the studies by Corey and Chaykovsky on their use for the preparation of strained rings …

Recent developments in vinylsulfonium and vinylsulfoxonium salt chemistry

M Mondal, S Chen, NJ Kerrigan - Molecules, 2018 - mdpi.com
This review describes advances in the literature since 2000 in the area of reactions of
vinylsulfonium and vinylsulfoxonium salts, with a particular emphasis on stereoselective …

Photoorganocatalytic synthesis of lactones via a selective C–H activation–alkylation of alcohols

N Kaplaneris, A Bisticha, GN Papadopoulos… - Green …, 2017 - pubs.rsc.org
Selective C–H activation is an area of growing importance in modern organic chemistry.
Herein, we report our efforts in combining organocatalysis and photocatalysis for the …

Ketenes as privileged synthons in the syntheses of heterocyclic compounds Part 2: Five-membered heterocycles

MM Heravi, B Talaei - Advances in heterocyclic chemistry, 2015 - Elsevier
Ketenes are mostly used as the remarkable and common starting materials for structurally
diverse five-membered and fused five-membered compounds, such as lactones, furans …

A copper-catalyzed diastereoselective O-transfer reaction of N-vinyl-α, β-unsaturated nitrones with ketenes into γ-lactones through [5+ 2] cycloaddition and N–O bond …

JY Liao, QY Wu, X Lu, N Zou, CX Pan, C Liang… - Green …, 2019 - pubs.rsc.org
A general protocol for the construction of novel densely functionalized γ-lactones was
developed in good to excellent yields with high diastereoselectivity from easily available N …

Catalyst‐and Substrate‐Dependent Chemodivergent Reactivity of Stabilised Sulfur Ylides with Salicylaldehydes

G Denisa Bisag, S Ruggieri, M Fochi… - Advanced Synthesis & …, 2021 - Wiley Online Library
Stabilised sulfur ylides are synthetically appealing compounds, which reactivity under
Brønsted acid catalysis has been poorly explored. Herein, we report a new catalyst‐and …

Flow Synthesis of Substituted γ-Lactones by Consecutive Photocatalytic/Reductive Reactions.

M Fagnoni, F Bonassi, A Palmieri… - Advanced …, 2014 - search.ebscohost.com
The article focuses on a study conducted on the flow synthesis of substituted gamma-
lactones through consecutive photocatalytic and reductive reactions. Flow reactors are used …

Selective continuous flow synthesis of hydroxy lactones from alkenoic acids

B Cerra, F Mangiavacchi, C Santi, AM Lozza… - Reaction Chemistry & …, 2017 - pubs.rsc.org
A novel approach to synthesize hydroxy lactones using flow chemistry is reported. The
system could be applied to a variety of functionalized alkenoic acids allowing the simple and …

Pd-Catalyzed Sequential Formation of C–C Bonds: A New Strategy for the Synthesis of (E)-α,β-Unsaturated Carbonyl Compounds from Sulfoxonium Ylides and 1 …

M Hu, Z Wu, B Yao, J Li, W Wu… - The Journal of Organic …, 2021 - ACS Publications
α, β-Unsaturated carbonyl compounds are significant moieties in many biological molecules
and have attracted considerable attention in organic synthetic chemistry. A Pd-catalyzed …

Asymmetric synthesis of γ-lactones through reaction of sulfoxonium ylides, aldehydes, and ketenes

NJ Peraino, HJ Ho, M Mondal, NJ Kerrigan - Tetrahedron Letters, 2014 - Elsevier
A method for the enantioselective synthesis of γ-lactones through the reaction of
enantioenriched sulfoxonium ylides, aldehydes, and ketenes was developed …