NHCs in main group chemistry

V Nesterov, D Reiter, P Bag, P Frisch, R Holzner… - Chemical …, 2018 - ACS Publications
Since the discovery of the first stable N-heterocyclic carbene (NHC) in the beginning of the
1990s, these divalent carbon species have become a common and available class of …

N-heterocyclic carbene adducts of main group elements and their use as ligands in transition metal chemistry

A Doddi, M Peters, M Tamm - Chemical reviews, 2019 - ACS Publications
N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …

Chalcogen bonding in crystalline diselenides and selenocyanates: From molecules of pharmaceutical interest to conducting materials

M Fourmigué, A Dhaka - Coordination Chemistry Reviews, 2020 - Elsevier
Organic diselenides are nowadays investigated for pharmaceutical applications, as well as
in material science in molecular (semi) conductors. In both application's domains, their …

Colloidal synthesis of cubic-phase copper selenide nanodiscs and their optoelectronic properties

J Choi, N Kang, HY Yang, HJ Kim… - Chemistry of …, 2010 - ACS Publications
High-quality copper selenide nanodiscs with a 2.6 nm thickness were prepared using
imidazoline-2-selenone as a new selenium precursor. The phase of prepared nanomaterials …

Reactions of 9-Carbene-9-Borafluorene Monoanion and Selenium: Synthesis of Boryl-Substituted Selenides and Diselenides

KE Wentz, A Molino, LA Freeman, DA Dickie… - Inorganic …, 2021 - ACS Publications
Reactions of 9-carbene-9-borafluorene monoanion (1) with elemental selenium and
selenium-containing reagents are reported. When compound 1 is reacted with grey …

N-Heterocyclic carbene stabilized parent sulfenyl, selenenyl, and tellurenyl cations (XH+, X= S, Se, Te)

LL Liu, D Zhu, LL Cao, DW Stephan - Dalton Transactions, 2017 - pubs.rsc.org
NHC-stabilized parent sulfenyl (H–S+), selenenyl (H–Se+) and tellurenyl (H–Te+) cations
have been achieved by treatment of NHC chalcogen adducts with trifluoromethanesulfonic …

Organometallic Hollow Spheres Bearing Bis (N‐Heterocyclic Carbene)–Palladium Species: Catalytic Application in Three‐Component Strecker Reactions

J Choi, HY Yang, HJ Kim, SU Son - Angewandte Chemie, 2010 - infona.pl
Innen hohl sind die sphärischen Katalysatoren, die durch Reaktion eines Tetraimidazolium‐
Bausteins mit Palladiumacetat unter Bildung eines dreidimensionalen Netzwerks hergestellt …

Iridium complexes containing bis (imidazoline thione) and bis (imidazoline selone) ligands for visible-light-induced oxidative coupling of benzylamines to imines

J Jin, HW Shin, JH Park, JH Park, E Kim, TK Ahn… - …, 2013 - ACS Publications
Novel iridium (III) complexes containing bis (N-heterocyclic carbene), bis (imidazoline
thione) L2, and bis (imidazoline selone) L3 were prepared. The iridium complexes bearing …

Chalcogen complexes of anionic N-heterocyclic carbenes

LP Ho, L Körner, T Bannenberg, M Tamm - Dalton Transactions, 2020 - pubs.rsc.org
Several group 16 adducts of the type [(WCA-IDipp) E] Li (solv.) that bear an anionic N-
heterocyclic carbene ligand with a weakly coordinating borate moiety (WCA-IDipp, WCA= B …

Recent developments in the chemistry of NHC-based selones: syntheses, applications and reactivity

S Yadav, R Deka, HB Singh - Chemistry Letters, 2019 - academic.oup.com
Selones, since their first report in 1963, have attracted significant interest with respect to their
bonding, structure and more importantly as an ancillary ligand for complexation with various …