Non‐equilibrium chemical systems underpin multiple domains of contemporary interest,
including supramolecular chemistry, molecular machines, systems chemistry, prebiotic …

Dynamic covalent synthesis aims to precisely control the assembly of simple building blocks
linked by reversible covalent bonds to generate a single, structurally complex product. In …

Over the last two decades ratchet mechanisms have transformed the understanding and
design of stochastic molecular systems—biological, chemical and physical—in a move away …

An energy ratchet mechanism is exploited for the synthesis of a molecule. In the presence of
adenosine triphosphate (ATP), hydrazone‐bond formation between an aldehyde and …

In a chemical equilibrium, the formation of high‐energy species—in a closed system—is
inefficient due to microscopic reversibility. Here, we demonstrate how this restriction can be …

Constitutional dynamic libraries (CDLs) of hydrazones, acylhydrazones, and imines undergo
reorganization and adaptation in response to chemical effectors (herein metal cations) via …

The overwhelming majority of artificial chemical reaction networks respond to stimuli by
relaxing towards an equilibrium state. The opposite response—moving away from …

With the advent of reversible covalent chemistry the study of the interplay between covalent
bond formation and noncovalent interactions has become increasingly relevant. Here we …

Biomimetic liposomes have a wide array of applications in several areas, ranging from
medicinal chemistry to synthetic biology. Due to their biocompatibility and biological …

For 24-atom triazine macrocycles, protonation of the heterocycle leads to a rigid, folded
structure presenting a network of hydrogen bonds. These molecules derive from dynamic …