The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

During the past decade we have witnessed the rapid development and understanding of
living radical polymerization (LRP)(or reversible deactivation radical polymerizations …

The mechanisms of most organic reactions are considered to proceed by two-electron
transfer pathways, even though both biology and radical chemistry rely extensively on one …

The most fundamental aspects of single-electron transfer (SET) principles are presented.
They are discussed according to different definitions used by expert practitioners and are …

A highly efficient photomediated atom transfer radical polymerization protocol is reported for
semi-fluorinated acrylates and methacrylates. Use of the commercially available solvent, 2 …

Cu (0)-mediated living radical polymerization or single electron transfer living radical
polymerization (Cu (0)-mediated LRP or SET-LRP) is a versatile polymerization technique …

The combination of copper (0) mediated living radical polymerization (Cu (0)-LRP) with thiol–
halogen, thiol–epoxy and copper catalysed alkyne azide coupling (CuAAC) click chemistry …

The synthesis of functional polymers encoded with biomolecules has been an extensive
area of research for decades. As such, a diverse toolbox of polymerization techniques and …

Single electron transfer–living radical polymerization (SET-LRP) represents a robust and
versatile tool for the synthesis of vinyl polymers with well-defined topology and chain end …

The versatile and high yielding functionalization of polymer end groups is a critical tool for
controlling material properties and/or for successful post polymerization reactions. In this …