Recent advances in confining polyoxometalates and the applications

L Guo, L He, Q Zhuang, B Li, C Wang, Y Lv, J Chu… - Small, 2023 - Wiley Online Library
Polyoxometalates (POMs) are widely used in catalysis, energy storage, biomedicine, and
other research fields due to their unique acidity, photothermal, and redox features. However …

Polyoxometalate based open-frameworks (POM-OFs)

HN Miras, L Vilà-Nadal, L Cronin - Chemical Society Reviews, 2014 - pubs.rsc.org
Polyoxometalate-based open frameworks (POM-OFs) are extended architectures
incorporating metal-oxide cluster units and comprise an emergent family of materials with a …

Heterogeneous catalysis by polyoxometalates in metal–organic frameworks

M Samaniyan, M Mirzaei, R Khajavian… - ACS …, 2019 - ACS Publications
The embedding of molecular metal oxides, or polyoxometalates (POMs), in metal–organic
frameworks (MOFs) opens new research avenues in catalysis and beyond. This review …

The intrinsic charge carrier behaviors and applications of polyoxometalate clusters based materials

L Yang, J Lei, JM Fan, RM Yuan, MS Zheng… - Advanced …, 2021 - Wiley Online Library
Polyoxometalates (POMs) are a series of molecular metal oxide clusters, which span the two
domains of solutes and solid metal oxides. The unique characters of POMs in structure …

Design and fabrication of memory devices based on nanoscale polyoxometalate clusters

C Busche, L Vila-Nadal, J Yan, HN Miras, DL Long… - Nature, 2014 - nature.com
Flash memory devices—that is, non-volatile computer storage media that can be electrically
erased and reprogrammed—are vital for portable electronics, but the scaling down of metal …

Polyoxometalate, cationic cluster, and γ-cyclodextrin: from primary interactions to supramolecular hybrid materials

MA Moussawi, N Leclerc-Laronze… - Journal of the …, 2017 - ACS Publications
Herein, we report on a three-component supramolecular hybrid system built from specific
recognition processes involving a Dawson-type polyoxometalate (POM),[P2W18O62] 6–, a …

Evolutionary metal oxide clusters for novel applications: toward high‐density data storage in nonvolatile memories

X Chen, Y Zhou, VAL Roy, ST Han - Advanced Materials, 2018 - Wiley Online Library
Because of current fabrication limitations, miniaturizing nonvolatile memory devices for
managing the explosive increase in big data is challenging. Molecular memories constitute …

Functionalization of oxide-free silicon surfaces with redox-active assemblies

B Fabre - Chemical Reviews, 2016 - ACS Publications
This review provides a comprehensive survey of the derivatization of hydrogen-terminated,
oxide-free silicon surfaces with electroactive assemblies (from molecules to polymers) …

Electron‐Sponge Nature of Polyoxometalates for Next‐Generation Electrocatalytic Water Splitting and Nonvolatile Neuromorphic Devices

W Ahmad, N Ahmad, K Wang, S Aftab, Y Hou… - Advanced …, 2024 - Wiley Online Library
Designing next‐generation molecular devices typically necessitates plentiful oxygen‐
bearing sites to facilitate multiple‐electron transfers. However, the theoretical limits of …

Solution-processed formation of DNA-origami-supported polyoxometalate multi-level switches with countercation-controlled conductance tunability

E Vogelsberg, M Moors, AS Sorokina… - Chemistry of …, 2023 - ACS Publications
We report a chemically programmed design and the switching characteristics of a functional
metal–DNA-origami–polyoxometalate (POM) material obtained from the solution-processed …