The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …

This Review summarizes the development of catalytic asymmetric dearomatization (CADA)
reactions. The CADA reactions discussed herein include oxidative dearomatization …

Abstract The 3, 3′‐disubstituted oxindole structural motif is a prominent feature in many
alkaloid natural products, which include all kinds of tetrasubstituted carbon stereocenters …

Oxindole has emerged as a valuable scaffold in medicinal chemistry possessing diverse
range of pharmacological activities. Its value has further been increased by its natural …

Asymmetric sigmatropic rearrangement is a powerful organic transformation via substrate-
reorganization to efficiently increase molecular complexity from readily accessible starting …

Described herein is a novel Brønsted acid catalyzed intramolecular hydroalkoxylation/
Claisen rearrangement, allowing the practical and atom‐economic synthesis of a range of …

The construction of 2, 2-disubstituted indolines has long presented a synthetic challenge
without any general solutions. Herein, we report a robust protocol for the dearomative …

In the presence of a chiral azolium salt (10 mol%), enols and ynals undergo a highly
enantioselective annulation reaction to form enantiomerically enriched dihydropyranones …

The Pd-catalyzed asymmetric allylic alkylation (AAA) is one of the most useful and versatile
methods for asymmetric synthesis known in organometallic chemistry. Development of this …

All in a sequence: An organocatalyzed Morita–Baylis–Hillman (MBH)/bromination/[3+ 2]
annulation sequence for highly stereoselective syntheses of bis (spirooxindole) s featuring …