2D electronic spectroscopic techniques for quantum technology applications

E Collini - The Journal of Physical Chemistry C, 2021 - ACS Publications
2D electronic spectroscopy (2DES) techniques have gained particular interest given their
capability of following ultrafast coherent and noncoherent processes in real-time. Although …

Vibronic and environmental effects in simulations of optical spectroscopy

TJ Zuehlsdorff, SV Shedge, SY Lu… - Annual Review of …, 2021 - annualreviews.org
Including both environmental and vibronic effects is important for accurate simulation of
optical spectra, but combining these effects remains computationally challenging. We outline …

Engineering couplings for exciton transport using synthetic DNA scaffolds

SM Hart, WJ Chen, JL Banal, WP Bricker, A Dodin… - Chem, 2021 - cell.com
Control over excitons enables electronic energy to be harnessed and transported for light
harvesting and molecular electronics. Such control requires nanoscale precision over the …

Unifying nonlinear response and incoherent mixing in action-2D electronic spectroscopy

M Bruschi, L Bolzonello, F Gallina… - The Journal of Physical …, 2023 - ACS Publications
Action-detection has expanded the scope and applicability of 2D electronic spectroscopy,
while posing new challenges for the unambiguous interpretation of spectral features. In this …

Polariton-assisted manipulation of energy relaxation pathways: donor–acceptor role reversal in a tuneable microcavity

D Dovzhenko, M Lednev, K Mochalov, I Vaskan… - Chemical …, 2021 - pubs.rsc.org
Resonant interaction between excitonic transitions of molecules and localized
electromagnetic field allows the formation of hybrid light–matter polaritonic states. This …

Coherence in carotenoid-to-chlorophyll energy transfer

E Meneghin, A Volpato, L Cupellini… - Nature …, 2018 - nature.com
The subtle details of the mechanism of energy flow from carotenoids to chlorophylls in
biological light-harvesting complexes are still not fully understood, especially in the ultrafast …

Engineering exciton dynamics with synthetic DNA scaffolds

SM Hart, J Gorman, M Bathe… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Excitons are the molecular-scale currency of electronic energy. Control over
excitons enables energy to be directed and harnessed for light harvesting, electronics, and …

Delocalized two-exciton states in DNA scaffolded cyanine dimers

PD Cunningham, SA Díaz, B Yurke… - The Journal of …, 2020 - ACS Publications
The engineering and manipulation of delocalized molecular exciton states is a key
component for artificial biomimetic light harvesting complexes as well as alternative circuitry …

DNA scaffold supports long-lived vibronic coherence in an indodicarbocyanine (Cy5) dimer

SH Sohail, JP Otto, PD Cunningham, YC Kim… - Chemical …, 2020 - pubs.rsc.org
Vibronic coupling between pigment molecules is believed to prolong coherences in
photosynthetic pigment–protein complexes. Reproducing long-lived coherences using …

DNA origami chromophore scaffold exploiting homoFRET energy transport to create molecular photonic wires

WP Klein, BS Rolczynski, SM Oliver… - ACS Applied Nano …, 2020 - ACS Publications
DNA-scaffolded molecular photonic wires (MPWs) displaying prearranged donor–acceptor
chromophore pairs that engage in extended Förster resonance energy transfer (FRET) …