Template-directed synthesis of molecular nanorings and cages

PS Bols, HL Anderson - Accounts of chemical research, 2018 - ACS Publications
Conspectus This Account is about templates as construction tools: molecules for making
molecules. A template organizes the reactants and provides information to promote …

Supramolecular chemistry: Host–guest molecular complexes

SB Khan, SL Lee - Molecules, 2021 - mdpi.com
In recent times, researchers have emphasized practical approaches for capturing
coordinated and selective guest entrap. The physisorbed nanoporous supramolecular …

A bola-type supra-amphiphile constructed from a water-soluble pillar [5] arene and a rod–coil molecule for dual fluorescent sensing

Y Yao, X Chi, Y Zhou, F Huang - Chemical Science, 2014 - pubs.rsc.org
A bola-type supra-amphiphile was successfully prepared and demonstrated to act as a dual
fluorescent sensor. It was constructed from a water-soluble pillar [5] arene (WP5) and an …

Supramolecular nesting of cyclic polymers

DV Kondratuk, LMA Perdigão, AMS Esmail… - Nature Chemistry, 2015 - nature.com
Advances in template-directed synthesis make it possible to create artificial molecules with
protein-like dimensions, directly from simple components. These synthetic macromolecules …

On-surface pseudo-high-dilution synthesis of macrocycles: principle and mechanism

Q Fan, T Wang, J Dai, J Kuttner, G Hilt, JM Gottfried… - ACS …, 2017 - ACS Publications
Macrocycles have attracted much attention due to their specific “endless” topology, which
results in extraordinary properties compared to related linear (open-chain) molecules …

Ultrafast delocalization of excitation in synthetic light-harvesting nanorings

CK Yong, P Parkinson, DV Kondratuk, WH Chen… - Chemical …, 2015 - pubs.rsc.org
Rings of chlorophyll molecules harvest sunlight remarkably efficiently during photosynthesis
in purple bacteria. The key to their efficiency lies in their highly delocalized excited states …

Tuning the mechanical behavior of metal–phenolic networks through building block composition

G Yun, JJ Richardson, M Biviano… - ACS applied materials & …, 2019 - ACS Publications
Metal–phenolic networks (MPNs) are an emerging class of functional metal–organic
materials with a high degree of modularity in terms of the choice of metal ion, phenolic …

Chromophores in molecular nanorings: When is a ring a ring?

P Parkinson, DV Kondratuk, C Menelaou… - The journal of …, 2014 - ACS Publications
The topology of a conjugated molecule plays a significant role in controlling both the
electronic properties and the conformational manifold that the molecule may explore. Fully π …

Molecular Quantum Rings Formed from a -Conjugated Macrocycle

CJ Judd, AS Nizovtsev, R Plougmann, DV Kondratuk… - Physical Review Letters, 2020 - APS
The electronic structure of a molecular quantum ring (stacks of 40-unit cyclic porphyrin
polymers) is characterized via scanning tunneling microscopy and scanning tunneling …

van der Waals-induced chromatic shifts in hydrogen-bonded two-dimensional porphyrin arrays on boron nitride

VV Korolkov, SA Svatek, A Summerfield, J Kerfoot… - Acs Nano, 2015 - ACS Publications
The fluorescence of a two-dimensional supramolecular network of 5, 10, 15, 20-tetrakis (4-
carboxylphenyl) porphyrin (TCPP) adsorbed on hexagonal boron nitride (hBN) is red-shifted …