Mechanism of generation of closo-decaborato amidrazones. Intramolecular non-covalent B–H⋯ π (Ph) interaction determines stabilization of the configuration around …

VK Burianova, DS Bolotin, AS Mikherdov… - New Journal of …, 2018 - pubs.rsc.org
Three types of N (H)-nucleophiles, viz. hydrazine, acetyl hydrazide, and a set of hydrazones,
were used to study the nucleophilic addition to the CN group of the 2-propanenitrilium closo …

Polypyridyl coordinated rhenium (I) tricarbonyl complexes as model devices for cancer diagnosis and treatment

L Moherane, OT Alexander, M Schutte-Smith… - Polyhedron, 2022 - Elsevier
This study reports on the solid-state structures, solution-state photoluminescence and in vitro
biological applications of fac-[Re (CO) 3 (N, N′-Bid)(X)] n where N, N′-Bid= 4, 4 …

Exploring the in vitro anticancer activities of Re (I) picolinic acid and its fluorinated complex derivatives on lung cancer cells: a structural study

ML Matlou, FP Malan, S Nkadimeng, L McGaw… - JBIC Journal of …, 2023 - Springer
Fifteen rhenium (I) tricarbonyl complexes of the form fac-[Re (N, O')(CO) 3 (X)], where N, O'-
bidentate ligand= 2-picolinic acid (Pico); 3, 5-difluoropyridine-2-carboxylic acid (Dfpc); 3 …

Aquation and anation kinetics of rhenium (I) dicarbonyl complexes: relation to cell toxicity and bioavailability

M Schutte-Smith, SC Marker, JJ Wilson… - Inorganic …, 2020 - ACS Publications
The aquation reactions of four rhenium (I) dicarbonyl complexes,[Re (CO) 2 (NN)(PR3)(Cl)],
where NN= 1, 10-phenanthroline (Phen) and 2, 9-dimethyl-1, 10-phenanthroline (DMPhen) …

Substitution reactivity and structural variability induced by tryptamine on the biomimetic rhenium tricarbonyl complex

FJF Jacobs, GJS Venter, E Fourie, RE Kroon, A Brink - RSC advances, 2021 - pubs.rsc.org
A series of seven fac-[Re (CO) 3 (5Me-Sal-Trypt)(L)] complexes containing tryptamine on the
N, O 5-methyl-salicylidene bidentate ligand backbone and where L is MeOH, Py, Imi, DMAP …

Nuclearity manipulation in Schiff-base fac-tricarbonyl complexes of Mn (I) and Re (I)

PP Mokolokolo, A Frei, MS Tsosane, DV Kama… - Inorganica Chimica …, 2018 - Elsevier
A range of bidentate Schiff-base ligands, 2-(cyclohexyliminomethyl) phenol, 2-(cyclopentyl)
methyl-5-methylphenol and 5-methyl-2-(phenylethyliminimethyl) phenol, with a variation in …

Solid State Isostructural Behavior and Quantified Limiting Substitution Kinetics in Schiff-Base Bidentate Ligand Complexes fac-[Re(O,N-Bid)(CO)3(MeOH)]n

A Brink, HG Visser, A Roodt - Inorganic Chemistry, 2014 - ACS Publications
A range of N, O-donor atom salicylidene complexes of the type fac-[M (O, N-Bid)(CO) 3 (L)] n
(O, N-Bid= anionic N, O-bidentate ligands; L= neutral coordinated ligand) have been …

New approach for the synthesis of water soluble fac-[MI (CO) 3]+ bis (diarylphosphino) alkylamine complexes (M= 99 Tc, Re)

DV Kama, A Frei, A Brink, H Braband, R Alberto… - Dalton …, 2021 - pubs.rsc.org
A novel proof-of-concept is reported to modify the water solubility and potential biological
effects of a bis (diphenylphosphino) alkylamine (PNP) ligand and the corresponding metal …

Induced fit activity-based sensing: a mechanistic study of pyrophosphate detection with a “flexible” Fe-salen complex

P Yadav, O Blacque, A Roodt, F Zelder - Inorganic Chemistry Frontiers, 2021 - pubs.rsc.org
Activity-based sensing of biological targets is attracting increasing attention. In this work, we
report detailed UV-Vis and fluorescence mechanistic studies on an Fe-salen based …

Self‐Assembled Multinuclear Complexes Incorporating 99mTc

A Frei, PP Mokolokolo, R Bolliger… - … A European Journal, 2018 - Wiley Online Library
Multinuclear complexes or clusters are rarely investigated in medicinal inorganic chemistry
although they represent structural intermediates between molecules and nanomaterials. We …