Single-atom catalysts (SACs) include a promising family of electrocatalysts with unique
geometric structures. Beyond conventional ones with fully isolated metal sites, an emerging …

Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Metal-metal bonding interactions can engender outstanding magnetic properties in bulk
materials and molecules, and examples abound for the transition metals. Extending this …

Homogeneous catalysis of organic transformations by metal complexes has been mostly
based on complexes of noble metals. In recent years, tremendous progress has been made …

Conspectus Nickel complexes exhibit distinct properties from other group 10 metals,
including a small nuclear radius, high paring energy, low electronegativity, and low redox …

Owing to the unknown correlation of a metal's ligand and its resulting preferred speciation in
terms of oxidation state, geometry, and nuclearity, a rational design of multinuclear catalysts …

Organometallic chemistry and its applications in homogeneous catalysis have been
dominated by mononuclear transition-metal complexes. The catalytic performance and …

Heterogenization of molecular catalysts via their immobilization within extended structures
often results in a lowering of their catalytic properties due to a change in their coordination …

Computational chemistry provides a versatile toolbox for studying mechanistic details of
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …

Metal complex catalysis, in which coordination compounds are designed as catalysts for
chemical transformations employing noncovalent interactions, is emerging as a powerful …