Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

S Rana, JP Biswas, S Paul, A Paik… - Chemical Society Reviews, 2021 - pubs.rsc.org
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Iron catalysis in organic synthesis

I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

[HTML][HTML] A review of new developments in the Friedel–Crafts alkylation–From green chemistry to asymmetric catalysis

M Rueping, BJ Nachtsheim - Beilstein Journal of Organic …, 2010 - beilstein-journals.org
The development of efficient Friedel–Crafts alkylations of arenes and heteroarenes using
only catalytic amounts of a Lewis acid has gained much attention over the last decade. The …

Iron (III)-catalyzed four-component coupling reaction of 1, 3-dicarbonyl compounds, amines, aldehydes, and nitroalkanes: a simple and direct synthesis of …

S Maiti, S Biswas, U Jana - The journal of organic chemistry, 2010 - ACS Publications
A simple, convenient, and multicomponent coupling strategy for the synthesis of highly
functionalized pyrroles catalyzed by iron (III) salts has been developed. This strategy …

Direct Nucleophilic SN1‐Type Reactions of Alcohols

E Emer, R Sinisi, MG Capdevila… - European Journal of …, 2011 - Wiley Online Library
Abstract In 2005, the ACS Green Chemistry Institute (GCI) and the global pharmaceutical
corporations developed the ACS GCI Pharmaceutical Roundtable to encourage the …

Iron‐Catalyzed C− O Bond Activation: Opportunity for Sustainable Catalysis

E Bisz, M Szostak - ChemSusChem, 2017 - Wiley Online Library
Oxygen‐based electrophiles have emerged as some of the most valuable cross‐coupling
partners in organic synthesis due to several major strategic and environmental benefits …

Synthesis, biological evaluation and molecular modeling study of pyrazole and pyrazoline derivatives as selective COX-2 inhibitors and anti-inflammatory agents. Part …

AA Magda, NI Abdel-Aziz, AM Alaa, AS El-Azab… - Bioorganic & medicinal …, 2012 - Elsevier
New pyrazole and pyrazoline derivatives have been synthesized and their ability to inhibit
ovine COX-1/COX-2 isozymes was evaluated using in vitro cyclooxygenase (COX) inhibition …

Alcohols as Substrates in Transition-Metal-Catalyzed Arylation, Alkylation, and Related Reactions

A Cook, SG Newman - Chemical Reviews, 2024 - ACS Publications
Alcohols are abundant and attractive feedstock molecules for organic synthesis. Many
methods for their functionalization require them to first be converted into a more activated …

Recent advances in the direct nucleophilic substitution of allylic alcohols through SN1-type reactions

A Baeza, C Najera - Synthesis, 2014 - thieme-connect.com
Direct nucleophilic substitution reactions of allylic alcohols are environmentally friendly,
since they generate only water as a byproduct, allowing access to new allylic compounds …

FeCl3-Catalyzed Highly Diastereoselective Synthesis of Substituted Piperidines and Tetrahydropyrans

A Guerinot, A Serra-Muns, C Gnamm… - Organic …, 2010 - ACS Publications
The eco-friendly and highly diastereoselective synthesis of substituted cis-2, 6-piperidines
and cis-2, 6-tetrahydropyrans is described. The key step of this method is the iron-catalyzed …