Solvation energies of the proton in methanol revisited and temperature effects

A Malloum, JJ Fifen, J Conradie - Physical Chemistry Chemical …, 2018 - pubs.rsc.org
We report in this work the absolute solvation enthalpies and the absolute solvation free
energies of the proton in methanol at temperatures ranging from 20 to 340 K and an …

Solution calorimetry of organic nonelectrolytes as a tool for investigation of intermolecular interactions

BN Solomonov, VB Novikov - Journal of Physical Organic …, 2008 - Wiley Online Library
The paper is mainly the review and generalization of the previous publications of the
authors. It demonstrates that solution calorimetry method gives the opportunities of more …

A new method for the extraction of specific interaction enthalpy from the enthalpy of solvation

BN Solomonov, VB Novikov… - Journal of physical …, 2005 - Wiley Online Library
A new, simple method for the extraction of specific interaction enthalpy from the enthalpy of
solvation is proposed. It is based on empirical but very general relationships describing the …

Compilation and correlation of limiting activity coefficients of nonelectrolytes in water

SR Sherman, DB Trampe, DM Bush… - Industrial & …, 1996 - ACS Publications
The phase equilibria of dilute aqueous solutions are treated separately from those of dilute
organic systems due to water's unique structure and hydrogen-bonding characteristics. As a …

Calculation of improved enthalpy and entropy of vaporization by a modified partition function in quantum cluster equilibrium theory

P Zaby, J Ingenmey, B Kirchner, S Grimme… - The Journal of Chemical …, 2021 - pubs.aip.org
In this work, we present an altered partition function that leads to an improved calculation of
the enthalpy and entropy of vaporization in the framework of quantum cluster equilibrium …

A new functional form for equations of state for some weakly associating fluids

M Thol, L Piazza, R Span - International Journal of Thermophysics, 2014 - Springer
A new functional form for equations of state for polar and weakly associating fluids was
developed. It was established with a simultaneous optimization algorithm developed …

Measurement and prediction of limiting activity coefficients

CA Eckert, SR Sherman - Fluid Phase Equilibria, 1996 - Elsevier
Limiting activity coefficients are of both theoretical and practical interest. They provide direct
information about unlike pair interactions in solution, without the need to use empirical gE …

Enthalpies of solution and excess enthalpies of oxo compounds by capillary gas chromatography

M Görgényi, K Héberger - Journal of chromatographic science, 1999 - academic.oup.com
The temperature dependence of retention data is measured for 5 n-alkanes and 35 aliphatic
ketones and aldehydes on capillary columns using 4 bonded stationary phases: dimethyl …

Application of MOSCED and UNIFAC to screen hydrophobic solvents for extraction of hydrogen-bonding organics from aqueous solution

TC Frank, JJ Anderson, JD Olson… - Industrial & engineering …, 2007 - ACS Publications
Liquid− liquid extraction using hydrophobic extraction solvents is a technology well-suited to
the removal of certain hydrogen-bonding organics from water or brine. Even when …

Linear solvation energy relationships to explain interactions responsible for solute adsorption onto a polar polymeric sorbent

BJ Brune, GF Payne, MV Chaubal - Langmuir, 1997 - ACS Publications
The industrial separations of low-valued bulk chemicals has relied on distillation for
separating volatile compounds and crystallization for the separation of nonvolatiles …