Boron and silicon-substituted 1, 3-dienes and dienophiles and their use in Diels-Alder reactions

ME Welker - Molecules, 2020 - mdpi.com
Boron and silicon-substituted 1, 3-dienes and boron and silicon-substituted alkenes and
alkynes have been known for years and the last 10 years have seen a number of new …

Synthesis and Application of Siloles: From the Past to Present

S Santra - ChemistrySelect, 2020 - Wiley Online Library
Heterocyclic compounds in particular siloles in which a carbon atom has been replaced by
an isovalent silicon atom, has gained wide attention recently. Due to their unique and …

Orientation and Alignment dynamics of polar molecule driven by shaped laser pulses

VV Nautiyal, S Devi, A Tyagi, B Vidhani, A Maan… - … Acta Part A: Molecular …, 2021 - Elsevier
We review the theoretical status of intense laser induced orientation and alignment-a field of
study which lies at the interface of intense laser physics and chemical dynamics and having …

Nonradiative relaxation mechanisms of the elusive silole molecule

DCA Valente, I Borges, TM Cardozo - Physical Chemistry Chemical …, 2021 - pubs.rsc.org
Silole derivatives have been extensively employed for developing organic optoelectronics,
but few studies focused on the photophysical properties of the silole molecule. In this work …

Chemical dynamics study on the gas-phase reaction of the D1-silylidyne radical (SiD; X 2 Π) with deuterium sulfide (D 2 S) and hydrogen sulfide (H 2 S)

SJ Goettl, S Doddipatla, Z Yang, C He… - Physical Chemistry …, 2021 - pubs.rsc.org
The reactions of the D1-silylidyne radical (SiD; X2Π) with deuterium sulfide (D2S; X1A1) and
hydrogen sulfide (H2S; X1A1) were conducted utilizing a crossed molecular beams machine …

Formation of 1-ethynyl-1 H-silole from the reaction of silicon atoms with benzene: matrix infrared spectroscopy and quantum chemical calculations

D Li, J Xu, X Xu, W Yang, J Jian - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
The reaction of silicon atoms with benzene molecules in solid neon is studied using matrix
isolation infrared spectroscopy. Aided by carbon-13 and deuterium isotopic shifts as well as …

A crossed molecular beams investigation of the reactions of atomic silicon (Si (3P)) with C4H6 isomers (1, 3-butadiene, 1, 2-butadiene, and 1-butyne)

AM Thomas, BB Dangi, T Yang, RI Kaiser, BJ Sun… - Chemical Physics, 2019 - Elsevier
The bimolecular gas phase reactions of ground state silicon (Si (3 P)) with the C 4 H 6
isomers 1, 3-butadiene, 1, 2-butadiene, and 1-butyne were investigated under single …

Formation of the 2, 3-Dimethyl-1-silacycloprop-2-enylidene Molecule via the Crossed Beam Reaction of the Silylidyne Radical (SiH; X2Π) with Dimethylacetylene …

T Yang, AM Thomas, BB Dangi, RI Kaiser… - The Journal of …, 2016 - ACS Publications
We carried out crossed molecular beam experiments and electronic structure calculations to
unravel the chemical dynamics of the reaction of the silylidyne (-d 1) radical (SiH/SiD; X2Π) …

DFT Characterization of Metallole-Decorated Silicon (001) Surface

C Kaderoğlu, S Ellıaltioğlu - The Journal of Physical Chemistry …, 2019 - ACS Publications
Multifunctional molecules have been important for being building blocks of interesting
molecular systems. A combination of these multifunctional molecules with conventional …