Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers

P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

The hydrophobic effect revisited—studies with supramolecular complexes imply high‐energy water as a noncovalent driving force

F Biedermann, WM Nau… - Angewandte Chemie …, 2014 - Wiley Online Library
Traditional descriptions of the hydrophobic effect on the basis of entropic arguments or the
calculation of solvent‐occupied surfaces must be questioned in view of new results obtained …

Cyclodextrins as building blocks for supramolecular structures and functional units

G Wenz - Angewandte Chemie International Edition in English, 1994 - Wiley Online Library
Cyclodextrins are frequently used as building blocks, because they can be linked both
covalently and noncovalently with specificity. Thus one, two, three, seven, fourteen …

Molecular view into the cyclodextrin cavity: Structure and hydration

AA Sandilya, U Natarajan, MH Priya - ACS omega, 2020 - ACS Publications
We find, through atomistic molecular dynamics simulation of native cyclodextrins (CDs) in
water, that although the outer surface of a CD appears like a truncated cone, the inner cavity …

Structures of the common cyclodextrins and their larger analogues beyond the doughnut

W Saenger, J Jacob, K Gessler, T Steiner… - Chemical …, 1998 - ACS Publications
If the amylose fraction of starch is degraded by glucosyltransferases, one or several turns of
the amylose helix are hydrolyzed off and their ends are joined together, thereby producing …

Hydrogen bonds and salt bridges across protein-protein interfaces.

D Xu, CJ Tsai, R Nussinov - Protein engineering, 1997 - academic.oup.com
To understand further, and to utilize, the interactions across protein-protein interfaces, we
carried out an analysis of the hydrogen bonds and of the salt bridges in a collection of 319 …

Evidence for resonance-assisted hydrogen bonding. 2. Intercorrelation between crystal structure and spectroscopic parameters in eight intramolecularly hydrogen …

V Bertolasi, P Gilli, V Ferretti, G Gilli - Journal of the American …, 1991 - ACS Publications
Crystal structure analysis of eight 1, 3-diaryl-1, 3-propanedione enols has been
accomplished with the aim of investigating in more detail the intramolecular hydrogen txmd …

Native and substituted cyclodextrins as chiral selectors for capillary electrophoresis enantioseparations: Structures, features, application, and molecular modeling

P Peluso, B Chankvetadze - Electrophoresis, 2021 - Wiley Online Library
CDs are cyclic oligosaccharides consisting of α‐d‐glucopyranosyl units linked through 1, 4‐
linkages, which are obtained from enzymatic degradation of starch. The coexistence of …

Thermal analysis of cyclodextrins and their inclusion compounds

F Giordano, C Novak, JR Moyano - Thermochimica Acta, 2001 - Elsevier
This review examines the literature concerning the thermal properties of natural and
semisynthetic cyclodextrins and their inclusion compounds. Particular emphasis is given to …

Direct dissolution of cellulose: background, means and applications

C Olsson, G Westman - Cellulose-fundamental aspects, 2013 - books.google.com
Being the main structural component in plants, cellulose is by far the most abundant organic
polymer on earth. The highest quantity of cellulose is found in the secondary walls of higher …