Chlorophylls make Earth green, are the central constituents in the engine of photosynthesis, and not surprisingly have garnered immense attention. A chlorin, the core chromophore of a …
This review covers the use of 2-azaallyl anions, 2-azaallyl cations, and 2-azaallyl radicals in organic synthesis up through June 2018. Particular attention is paid to both foundational …
ATPC Gomes, MG Neves… - Anais da Academia …, 2018 - SciELO Brasil
This review has two parts. The first one gives an approach to interdisciplinary studies against cancer carried out by many scientists using porphyrin-type substrates as …
Y Ning, J Tang, YW Liu, J Jing, Y Sun, JL Zhang - Chemical Science, 2018 - pubs.rsc.org
Herein, we report the design and synthesis of biocompatible Yb3+ complexes for near- infrared (NIR) living cell imaging. Upon excitation at either the visible (Soret band) or red …
Porphyrinoids are robust heterocyclic dyes studied extensively for their applications in medicine and as photonic materials because of their tunable photophysical properties …
Since the early work of Fischer, porphyrin chemistry has evolved dramatically allowing many exotic macrocycles to be synthesised. 1 Few boundaries restrict the porphyrin chemist, as …
JIT Costa, AC Tome, MG Neves… - Journal of porphyrins …, 2011 - World Scientific
5, 10, 15, 20-tetrakis (pentafluorophenyl) porphyrin reacts with a range of nucleophiles (amines, alcohols, thiols, nitrogen heterocycles, and others) resulting in the nucleophilic …
J Hernández-Gil, CY Chow, H Chatras… - Journal of the …, 2023 - ACS Publications
We report an innovative approach to producing bacteriochlorins (bacs) via formal cycloaddition by subjecting a porphyrin to a trimolecular reaction. Bacs are near-infrared …
X Fu, Y Meng, X Li, M Stępień… - Chemical …, 2018 - pubs.rsc.org
The antiaromatic ring of norcorrole, a contracted tetrapyrrolic porphyrinoid, was subjected to [2+ 3] dipolar cycloaddition of iminonitriles. The paratropic character of the resulting chiral …