Studies on the chemical reduction of polynuclear titanium (IV) nitrido complexes
J Caballo, A Calvo-Molina, S Claramonte… - Dalton …, 2024 - pubs.rsc.org
The redox chemistry of cube-type titanium (IV) nitrido complexes [{Ti4 (η5-C5Me5) 3 (R)}(μ3-
N) 4](R= η5-C5Me5 (1), N (SiMe3) 2 (2), η5-C5H4SiMe3 (3), and η5-C5H5 (4)) was …
N) 4](R= η5-C5Me5 (1), N (SiMe3) 2 (2), η5-C5H4SiMe3 (3), and η5-C5H5 (4)) was …
Cleavage of dinitrogen from forming gas by a titanium molecular system under ambient conditions
M González‐Moreiras, M Mena… - … A European Journal, 2017 - Wiley Online Library
Simple exposure of a hexane solution of [TiCp* Me3](Cp*= η5‐C5Me5) to an atmosphere of
commercially available and inexpensive forming gas (H2/N2 mixture, 13.5–16.5% of H2) at …
commercially available and inexpensive forming gas (H2/N2 mixture, 13.5–16.5% of H2) at …
Heterometallic Cube‐Type Molecular Nitrides
M Mena, A Pérez‐Redondo… - European Journal of …, 2016 - Wiley Online Library
Polynuclear transition‐metal nitrido complexes constitute a class of molecular cage
compounds with fascinating structures and interesting bonding properties. However, there is …
compounds with fascinating structures and interesting bonding properties. However, there is …
Cooperative Lewis Pairs Based on High-Valent Early Transition Metal Halides and Synthesis of Their Nitride Complexes
MM Rahman - 2018 - search.proquest.com
Herein, we report the activation of relatively strong C–H and C–O bonds under mild
conditions by a cooperative interaction of TaCl 5 and PPh 3. An unprecedented activation of …
conditions by a cooperative interaction of TaCl 5 and PPh 3. An unprecedented activation of …