Asymmetric catalysis with chiral metal complexes has received considerable attention in
recent years, and its contribution to the art of organic synthesis has become of leading …

The synthesis of silicon-stereogenic silanes is undoubtedly one of the most intriguing and
challenging aspects in organic chemistry and organosilicon chemistry and is neglected by …

Despite the growing demand for the enantioenriched silicon-stereogenic silanols in
materials science, medicinal chemistry, and modern synthetic chemistry, the catalytic …

A rhodium-catalyzed enantioselective construction of triorgano-substituted silicon-
stereogenic siloxanes and alkoxysilanes is developed. This process undergoes a direct …

Enantiopure monohydrosilanes are versatile chiral reagents for alcohol resolution and
mechanistic investigation. Herein, we have demonstrated the asymmetric synthesis of …

Despite growing progress in the construction of chiral organosilicon compounds, the
catalytic asymmetric synthesis of silicon‐stereogenic silanols is less explored and remains a …

Si goes chiral: Treatment of a bis (biphenyl) silane with a catalytic amount of a rhodium
complex gave a spirosilabifluorene bearing a quaternary silicon atom. By using a rhodium …

The strategic carbon‐to‐silicon substitution at a stereogenic center can produce chiral
silanes with significantly improved properties relative to their carbon congeners. We herein …

A Pd-catalyzed asymmetric synthesis of Si-stereogenic dibenzosiloles is developed through
enantioselective C–H bond functionalization of prochiral 2-(arylsilyl) aryl triflates. High …

We report a method to construct chiral tetraorganosilicons by tandem silacyclobutane (SCB)
desymmetrization–dehydrogenative silylations. A wide array of dibenzosiloles with …