Indolyl Phosphine Nickel(II) Fluorido Complexes: Synthesis and Intermediates in Suzuki–Miyaura Cross‐Coupling Reactions

O He, B Cula, T Braun - Helvetica Chimica Acta, 2023 - Wiley Online Library
The C− F bond activation of pentafluoropyridine and 2, 3, 5, 6‐tetrafluoropyridine at [Ni (cod)
2](cod= 1, 5‐cyclooctadiene) in the presence of the phosphine PPh2 (Ind)(Ind= 3‐methyl‐2 …

Unusual Changes of C− H Bond Lengths in Chiral Zinc Complexes Induced by Noncovalent Interactions

V Elakkat, E Tessema, CH Lin, X Wang… - Angewandte …, 2023 - Wiley Online Library
In order to better understand the effect of non‐covalent weak interactions on molecules, we
have explored a variety of weak interactions, such as improper H‐bonding (HB), tetrel bonds …

Synthesis, structure and non-covalent interactions of trans-[2-(HCF2 (CF2) 3CH2OCH2) 2-py-PdCl2] complex: rare C− F⋯ F− C halogen bonds and blue-shifting C− H …

G Gurumallappa, CF Chiu, CL Ho, HC Chang… - Journal of Molecular …, 2024 - Elsevier
The sp 3-based C− F⋯ F− C halogen bonds (XBs) and blue-shifting C− H⋯ X (X= F, Cl)
hydrogen bonds (HBs) are a relatively unusual phenomenon in chemistry, due to their …

Short-chained platinum complex catalyzed hydrosilylation under thermomorphic conditions: heterogeneous phase separation at ice temperature

CF Chiu, JH Ho, E Tessema, Y Lu, CR Shen, CW Lin… - Molecules, 2021 - mdpi.com
Homogeneous catalysts PtCl2 [5, 5′-bis-(n-ClCF2 (CF2) 3CH2OCH2)-2, 2′-bpy](2A) and
PtCl2 [5, 5′-bis-(n-HCF2 (CF2) 3CH2OCH2)-2, 2′-bpy](2B), which contained short …

Synthesis, luminescence, and structure of a polymorphic polyfluorinated diiodoplatinum (ii) diimine complex

NM Barker, YX Li, MM Lee, CR Shen… - Inorganic …, 2019 - ACS Publications
PtI2 (5, 5′-bis (HCF2CH2OCH2)-2, 2′-bpy)], 55-2FH-PtI 2, is the first example of a
substituted fluorinated diiodoplatinum diimine complex that exhibits polymorphism. The …