Towards functionalized lignin and its derivatives for high-value material applications

X Yu, B Yang, W Zhu, T Deng, Y Pu… - Industrial Crops and …, 2023 - Elsevier
In pursuit of low-carbon development, the production of diverse functional materials from
renewable resources, especially lignocellulosic biomass, is of vital importance. Lignin is a …

Degradation of thiacloprid via unactivated peroxymonosulfate: The overlooked singlet oxygen oxidation

T Liu, D Zhang, K Yin, C Yang, S Luo… - Chemical Engineering …, 2020 - Elsevier
Unactivated peroxymonosulfate (PMS) degrading organic contaminants has been reported.
Previous studies have focused on direct PMS oxidation, while the role of singlet oxygen (1 O …

A human exposome framework for guiding risk management and holistic assessment of recycled water quality

E Garner, N Zhu, L Strom, M Edwards… - … Science: Water Research …, 2016 - pubs.rsc.org
Challenges associated with water scarcity and increasing water demand are leading many
cities around the globe to consider water reuse as a step towards water sustainability …

Peroxymonosulfate oxidizes amino acids in water without activation

M Ruiz, Y Yang, CA Lochbaum… - Environmental …, 2019 - ACS Publications
A variety of peptidic and proteinaceous contaminants (eg, proteins, toxins, pathogens)
present in the environment may pose risk to human health and wildlife. Peroxymonosulfate …

Nucleophilicity of glutathione: a link to Michael acceptor reactivities

RJ Mayer, AR Ofial - Angewandte Chemie International Edition, 2019 - Wiley Online Library
Deprotonated glutathione is among the most potent biological nucleophiles and plays an
important physiological role in cellular detoxification by forming covalent conjugates with …

Remediation of trichloroethylene contaminated soil by unactivated peroxymonosulfate: Implication on selected soil characteristics

BT Oba, X Zheng, MA Aborisade, J Liu… - Journal of …, 2021 - Elsevier
The advanced oxidation process (AOP) based on activated Peroxymonosulfate (PMS) has
been attracting many people in the field of soil and water remediation in many ways while …

Highly Chemoselective Deoxygenation of N-Heterocyclic N-Oxides Using Hantzsch Esters as Mild Reducing Agents

JH An, KD Kim, JH Lee - The Journal of Organic Chemistry, 2021 - ACS Publications
Herein, we disclose a highly chemoselective room-temperature deoxygenation method
applicable to various functionalized N-heterocyclic N-oxides via visible light-mediated …

Hydrogen Peroxide-Assisted Alkaline Defluorination of the Fumigant and Potent Greenhouse Gas, Sulfuryl Fluoride: Hydrogen Peroxide as a Nucleophilic Reagent

Z Chen, C Wang, SM Allabakshi… - … Science & Technology, 2024 - ACS Publications
Sulfuryl fluoride (SO2F2, SF) is an effective and increasingly popular fumigant for treating
buildings and commodities in international trade but has come under scrutiny as a potent …

Mechanism of unactivated peroxymonosulfate-induced degradation of methyl parathion: Kinetics and transformation pathway

X Liao, J Cao, Y Hu, C Zhang, L Hu - Chemosphere, 2021 - Elsevier
Although various activated peroxymonosulfate (PMS) processes have been applied widely
for the destruction of recalcitrant organics due to its high generation potential of various …

Influence of solvent mixture on nucleophilicity parameters: the case of pyrrolidine in methanol–acetonitrile

S Souissi, W Gabsi, A Echaieb, J Roger, JC Hierso… - RSC …, 2020 - pubs.rsc.org
The course of organic chemical reactions is efficiently modelled through the concepts of
“electrophiles” and “nucleophiles”(meaning electron-seeking and nucleus-seeking reactive …