Catalytic asymmetric cyanation reactions

N Kurono, T Ohkuma - Acs Catalysis, 2016 - ACS Publications
Catalytic asymmetric cyanations of prochiral unsaturated compounds affording the
corresponding nitrile products in high enantiomeric excess (≥ 90% in general) are …

Organocatalytic synthesis of α-aminonitriles: a review

B Ullah, NK Gupta, Q Ke, N Ullah, X Cai, D Liu - Catalysts, 2022 - mdpi.com
α-Aminonitriles, which have anticancer, antibacterial, antiviral, and antifungal properties,
have played an important role in pharmacology. Furthermore, they can also be used to …

Structural Dynamism-Actuated Reversible CO2 Adsorption Switch and Postmetalation-Induced Visible Light Cα–H Photocyanation with Rare Size Selectivity in N …

G Kumar, M Singh, R Goswami… - ACS Applied Materials & …, 2020 - ACS Publications
The impact of dimensionality and flexibility on anticipated properties has prompted major
research focus to three-dimensional covalent organic frameworks (3D COFs), where astute …

Asymmetric Strecker reactions catalyzed by thiourea phosphonium and ammonium salts

H Wang, K Wang, Y Ren, N Li, B Tang… - Advanced Synthesis & …, 2017 - Wiley Online Library
The application of asymmetric phase‐transfer catalysis to the Strecker reaction of ketimines
was realized utilizing bifunctional thiourea‐phosphonium salts. The asymmetric Strecker …

Enantioselective synthesis of pyrazolone α-aminonitrile derivatives via an organocatalytic Strecker reaction

S Mahajan, P Chauhan, U Kaya, K Deckers… - Chemical …, 2017 - pubs.rsc.org
A new organocatalytic enantioselective Strecker reaction of pyrazolone-derived ketimine
electrophiles has been developed. Using pseudo-enantiomeric squaramide catalysts the …

Experimental and computational studies of laterally ethoxy Schiff base-ester liquid crystalline magnets

WJ Teoh, NAJ Tun Nur Iskandar, GY Yeap… - Liquid …, 2022 - Taylor & Francis
ABSTRACT A series of liquid crystals 4-X-(3'-ethoxy-4'-alkyoxyphenyimino) anilines with
elongated molecular axis through the introduction of alkoxy chains containing different …

Organocatalytic Enantioselective Strecker Reaction with Seven‐Membered Cyclic Imines

C Lluna‐Galán, G Blay, I Fernández… - Advanced Synthesis …, 2018 - Wiley Online Library
A highly enantioselective Strecker reaction with dibenzo [b, f][1, 4] oxazepines has been
described using a dihydroquinine‐derived thiourea as organocatalyst. The reaction affords …

Natural low-molecular mass organic compounds with oxidase activity as organocatalysts

T Nishiyama, Y Hashimoto… - Proceedings of the …, 2014 - National Acad Sciences
Organocatalysts, low-molecular mass organic compounds composed of nonmetallic
elements, are often used in organic synthesis, but there have been no reports of …

Enantioselective Strecker and Allylation Reactions with Aldimines Catalyzed by Chiral Oxazaborolidinium Ions

KT Kang, SH Park, DH Ryu - Organic letters, 2019 - ACS Publications
Chiral oxazaborolidinium ion (COBI)-catalyzed enantioselective nucleophilic addition
reactions of aldimines using tributyltin cyanide and allyltributylstannane have been …

Biocatalytic approach to chiral β-nitroalcohols by enantioselective alcohol dehydrogenase-mediated reduction of α-nitroketones

F Tentori, E Brenna, D Colombo, M Crotti, FG Gatti… - Catalysts, 2018 - mdpi.com
Chiral β-nitroalcohols are important building blocks in organic chemistry. The synthetic
approach that is based on the enzyme-mediated reduction of α-nitroketones has been …