Solid‐state post Li metal ion batteries: a sustainable forthcoming reality?
S Ferrari, M Falco, AB Muñoz‐García… - Advanced Energy …, 2021 - Wiley Online Library
In the quest for a sustainable society, energy storage technology is destined to play a central
role in the future energy landscape. Breakthroughs in materials and methods involving …
role in the future energy landscape. Breakthroughs in materials and methods involving …
Interfaces and interphases in Ca and Mg batteries
JD Forero‐Saboya, DS Tchitchekova… - Advanced Materials …, 2022 - Wiley Online Library
The development of high energy density battery technologies based on divalent metals as
the negative electrode is very appealing. Ca and Mg are especially interesting choices due …
the negative electrode is very appealing. Ca and Mg are especially interesting choices due …
Correlation between electrolyte chemistry and solid electrolyte interphase for reversible Ca metal anodes
The development of rechargeable Ca metal batteries (RCMBs) is hindered by the Ca2+
passivating solid electrolyte interphases (SEIs). The cation solvation structure dictated by …
passivating solid electrolyte interphases (SEIs). The cation solvation structure dictated by …
Room-temperature calcium plating and stripping using a perfluoroalkoxyaluminate anion electrolyte
Multivalent ion chemistries, like Ca2+, used in energy storage boast the potential to utilize
solid metallic anodes and provide high volumetric energy density. The promise of such …
solid metallic anodes and provide high volumetric energy density. The promise of such …
Realizing Wide-Temperature Reversible Ca Metal Anodes through a Ca2+-Conducting Artificial Layer
Room-temperature Ca deposition/stripping is impeded by the formation of ionic insulating
interfaces. Electrolyte optimization could partially enhance Ca reversibility by tailoring the …
interfaces. Electrolyte optimization could partially enhance Ca reversibility by tailoring the …
Investigating the abnormal conductivity behaviour of divalent cations in low dielectric constant tetraglyme-based electrolytes
Solutions made of tetraglyme (G4) containing Ca (TFSI) 2 have been studied as models to
understand the solvation structure and the conductivity properties of multivalent ions in low …
understand the solvation structure and the conductivity properties of multivalent ions in low …
High-solvation electrolytes for ultra-stable calcium-ion storage
Calcium-ion batteries (CIBs) have potential as electrochemical energy storage devices due
to the low redox potential of Ca2+/Ca and the abundant reserves of Ca. However, the …
to the low redox potential of Ca2+/Ca and the abundant reserves of Ca. However, the …
New perspectives on the multianion approach to adapt electrode materials for lithium and post-lithium batteries
C Pérez-Vicente, R Alcántara - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Developing new and sustainable batteries is essential for modern society. Both cationic
doping (eg transition metals) and anionic doping (F−, O2−, S2−, PO43−, etc.) can be …
doping (eg transition metals) and anionic doping (F−, O2−, S2−, PO43−, etc.) can be …
Concentration-dependent ion correlations impact the electrochemical behavior of calcium battery electrolytes
Ion interactions strongly determine the solvation environments of multivalent electrolytes
even at concentrations below that required for practical battery-based energy storage. This …
even at concentrations below that required for practical battery-based energy storage. This …
Reductive Decomposition Kinetics and Thermodynamics That Govern the Design of Fluorinated Alkoxyaluminate/Borate Salts for Mg-Ion and Ca-Ion Batteries
The rational design of electrolytes has been a long-standing challenge in chemistry and
materials science. In this work, we demonstrate a computational rationale for improving the …
materials science. In this work, we demonstrate a computational rationale for improving the …