Low oxidation state and hydrido group 2 complexes: synthesis and applications in the activation of gaseous substrates

MJ Evans, C Jones - Chemical Society Reviews, 2024 - pubs.rsc.org
Numerous industrial processes utilise gaseous chemical feedstocks to produce useful
chemical products. Atmospheric and other small molecule gases, including anthropogenic …

Diberyllocene, a stable compound of Be (I) with a Be–Be bond

JT Boronski, AE Crumpton, LL Wales, S Aldridge - Science, 2023 - science.org
The complex diberyllocene, CpBeBeCp (Cp, cyclopentadienyl anion), has been the subject
of numerous chemical investigations over the past five decades yet has eluded experimental …

Recent progress in beryllium organometallic chemistry

D Parveen, RK Yadav, DK Roy - Chemical Communications, 2024 - pubs.rsc.org
Beryllium possesses a unique amalgamation of characteristics, its electronegativity
included, that not only make it a vital component in a wide range of technical sectors and …

Inducing nucleophilic reactivity at beryllium with an aluminyl ligand

JT Boronski, LR Thomas-Hargreaves… - Journal of the …, 2023 - ACS Publications
The reactions of anionic aluminium or gallium nucleophiles {K [E (NON)]} 2 (E= Al, 1; Ga, 2;
NON= 4, 5-bis (2, 6-diisopropylanilido)-2, 7-di tert-butyl-9, 9-dimethylxanthene) with …

Reply to the 'Comment on “The oxidation state in low-valent beryllium and magnesium compounds”'by S. Pan and G. Frenking, Chem. Sci., 2022, 13

M Gimferrer, S Danés, E Vos, CB Yildiz, I Corral… - Chemical …, 2023 - pubs.rsc.org
A recent article by Pan and Frenking challenges our assignment of the oxidation state of low
valent group 2 compounds. With this reply, we show that our assignment of Be (+ 2) and Mg …

Gauging radical stabilization with carbenes

K Breitwieser, H Bahmann, R Weiss… - Angewandte Chemie …, 2022 - Wiley Online Library
Carbenes, including N‐heterocyclic carbene (NHC) ligands, are used extensively to
stabilize open‐shell transition metal complexes and organic radicals. Yet, it remains …

Comment on “The oxidation state in low-valent beryllium and magnesium compounds” by M. Gimferrer, S. Danés, E. Vos, CB Yildiz, I. Corral, A. Jana, P. Salvador and …

S Pan, G Frenking - Chemical Science, 2023 - pubs.rsc.org
We challenge the assignment of the oxidation state+ 2 for beryllium and magnesium in the
complexes Be (cAACDip) 2 and Mg (cAACDip) 2 as suggested by Gimferrer et al., Chem …

Oxidation States: Intrinsically Ambiguous?

IF Leach, JEMN Klein - ACS central science, 2024 - ACS Publications
The oxidation state (OS) formalism is a much-appreciated good in chemistry, receiving wide
application. However, like all formalisms, limitations are inescapable, some of which have …

Heterobimetallic alkaline earth metal–metal bonding

J Mai, J Maurer, J Langer, S Harder - Nature Synthesis, 2024 - nature.com
Low-oxidation-state complexes of type (BDI) Mg–Mg (BDI)(BDI, β-diketiminate) show broad
reactivity, finding application as soluble, universal reducing agents, enriching the field of …

Beryllium-centred C–H activation of benzene

KG Pearce, MS Hill, MF Mahon - Chemical Communications, 2023 - pubs.rsc.org
Reaction of BeCl2 with the dilithium diamide,[{SiNDipp} Li2]({SiNDipp}={CH2SiMe2NDipp}
2), provides the dimeric chloroberyllate,[{SiNDippBeCl} Li] 2, en route to the 2-coordinate …