The worldwide urge to embrace a sustainable and bio-compatible chemistry has led industry
and academia to develop of chlorine-free methodologies focused on the use of CO2 and …

In this review the reactivity of the bio-based platform compounds D-sorbitol and isosorbide
with green reagents and solvent dimethyl carbonate (DMC) is reported. Dehydration of D …

Vollautomatisch: Mit einer Kombination aus automatisiertem Flussreaktor, Online‐Analyse
und Steuerungsalgorithmus (siehe schematischen Aufbau) gelingt die effiziente …

DBU (1, 8-diazabicyclo [5.4. 0] undec-7-ene) is an active catalyst of poly (bisphenol A
carbonate)(PC) alcoholysis and promotes selectively and quantitatively the solvent-free (no …

The activation of C–H bonds is a central challenge in organic chemistry and usually a key
step for the retro-synthesis of functional natural products due to the high chemical stability of …

Abstract Poly (isosorbide carbonate)(PIC) was synthesized by melt polycondensation of
dimethyl carbonate (DMC) and isosorbide using lithium acetylacetonate (LiAcac) as the …

2, 5-furandicarboxylic acid (FDCA) is one of the most studied bio-based monomers, being
considered the best substitute for fossil-derived terephthalic acid in plastic production. FDCA …

It is an immense challenge to design catalysts for synthesizing high molecular weight
polycarbonates using CO2, CO2-based compounds, or biorenewable chemicals as building …

Transesterification of dimethyl carbonate with glycerol has been investigated using various
ionic liquids as catalysts. Synthesis of glycidol with high selectivity (78%) has been achieved …

The synthesis of high-molecular-weight bioderived polycarbonates via green routes and
regulation of molecular weight is of great significance and is highly challenging. Herein, a …