State of the art and perspectives in heterogeneous catalysis of CO 2 hydrogenation to methanol

J Zhong, X Yang, Z Wu, B Liang, Y Huang… - Chemical Society …, 2020 - pubs.rsc.org
The ever-increasing amount of anthropogenic carbon dioxide (CO2) emissions has resulted
in great environmental impacts. The selective hydrogenation of CO2 to methanol, the first …

[HTML][HTML] Nanoparticle shapes by using Wulff constructions and first-principles calculations

GD Barmparis, Z Lodziana, N Lopez… - Beilstein journal of …, 2015 - beilstein-journals.org
Background: The majority of complex and advanced materials contain nanoparticles. The
properties of these materials depend crucially on the size and shape of these nanoparticles …

Steam reforming of methanol for hydrogen production: A critical analysis of catalysis, processes, and scope

AM Ranjekar, GD Yadav - Industrial & Engineering Chemistry …, 2021 - ACS Publications
The hydrogen economy is being pursued quite vigorously since hydrogen is an important
and green energy source with a variety of applications as fuel for transportation, fuel cell …

Atom-resolved imaging of dynamic shape changes in supported copper nanocrystals

PL Hansen, JB Wagner, S Helveg, JR Rostrup-Nielsen… - Science, 2002 - science.org
In situ transmission electron microscopy is used to obtain atom-resolved images of copper
nanocrystals on different supports. These are catalysts for methanol synthesis and …

Active sites and structure–activity relationships of copper-based catalysts for carbon dioxide hydrogenation to methanol

S Natesakhawat, JW Lekse, JP Baltrus… - Acs catalysis, 2012 - ACS Publications
Active sites and structure–activity relationships for methanol synthesis from a stoichiometric
mixture of CO2 and H2 were investigated for a series of coprecipitated Cu-based catalysts …

Methanol–steam reforming on Cu/ZnO/Al2O3 catalysts. Part 2. A comprehensive kinetic model

BA Peppley, JC Amphlett, LM Kearns… - Applied Catalysis A …, 1999 - Elsevier
Surface mechanisms for methanol–steam reforming on Cu/ZnO/Al2O3 catalysts are
developed which account for all three of the possible overall reactions: methanol and steam …

In situ investigations of structural changes in Cu/ZnO catalysts

JD Grunwaldt, AM Molenbroek, NY Topsøe, H Topsøe… - Journal of …, 2000 - Elsevier
Dynamic changes in the structure and catalytic activity of Cu/ZnO methanol synthesis
catalysts have been investigated by a further developed in situ method, which combines X …

Operando high-pressure investigation of size-controlled CuZn catalysts for the methanol synthesis reaction

NJ Divins, D Kordus, J Timoshenko, I Sinev… - Nature …, 2021 - nature.com
Abstract Although Cu/ZnO-based catalysts have been long used for the hydrogenation of
CO2 to methanol, open questions still remain regarding the role and the dynamic nature of …

Improving the Cu/ZnO-based catalysts for carbon dioxide hydrogenation to methanol, and the use of methanol as a renewable energy storage media

UJ Etim, Y Song, Z Zhong - Frontiers in Energy Research, 2020 - frontiersin.org
Heterogeneous catalytic hydrogenation of carbon dioxide (CO2) to methanol is a practical
approach to mitigating its greenhouse effect in the environment while generating good …

The role of copper particle size in low pressure methanol synthesis via CO 2 hydrogenation over Cu/ZnO catalysts

A Karelovic, P Ruiz - Catalysis Science & Technology, 2015 - pubs.rsc.org
Cu/ZnO catalysts with different mean Cu particle sizes were prepared by wet impregnation of
copper nitrate onto a zinc oxide support. Their performance was studied in methanol …