Heterogenization of homogeneous catalysts in polymer nanoparticles: From easier recovery and reuse to more efficient catalysis

T Chen, Y Peng, M Qiu, C Yi, Z Xu - Coordination Chemistry Reviews, 2023 - Elsevier
Commercially available polymer resins such as Merrifield resin have been extensively used
as supports in the heterogenization of homogenous catalysts, allowing easier recovery and …

Polypentenamer renaissance: challenges and opportunities

WJ Neary, JG Kennemur - ACS Macro Letters, 2018 - ACS Publications
This Viewpoint highlights the viability and increasing variety of functionalized
polypentenamers as unique and valuable materials created through enthalpy-driven ring …

Variable temperature ROMP: Leveraging low ring strain thermodynamics to achieve well-defined polypentenamers

WJ Neary, JG Kennemur - Macromolecules, 2017 - ACS Publications
Living-like conditions through ring-opening metathesis polymerization (ROMP) of low ring
strain monomers were achieved through temperature variation during the reaction. For a …

Polystyrene nanoparticles prepared by nanoprecipitation: A recyclable template for fabricating hollow silica

KB Vu, TK Phung, TTT Tran, C Mugemana… - Journal of Industrial and …, 2021 - Elsevier
Polystyrene was synthesized and applied as a template for fabricating hollow silica
nanoparticles. Organic solvent and water were used as a solvent and an anti-solvent …

Well-defined and precision-grafted bottlebrush polypentenamers from variable temperature ROMP and ATRP

WJ Neary, BA Fultz, JG Kennemur - ACS Macro Letters, 2018 - ACS Publications
Polypentenamer macroinitiators are synthesized through variable temperature ring opening
metathesis polymerization of 3-cyclopentenyl α-bromoisobutyrate, which has sufficient ring …

Arm-first synthesis of hyperbranched-core star polymers via copper-catalyzed azide-alkyne cycloaddition

KM Fuller, D Clay, SR Almahdali, A Paterson… - European Polymer …, 2023 - Elsevier
A general method for the arm-first synthesis of star polymers through a formal A 2+ B 3 step-
growth process is introduced. The synthesis relies on copper-catalyzed azide-alkyne …

Trifunctional Trimethyl Citrate Modified Poly (ethylene terephthalate) with Enhanced Tensile Strength and Elongation

S Sun, W Sun, R Zhang, Y Ding… - Industrial & …, 2023 - ACS Publications
The reinforcement of thermoplastic polyester is very valuable in the fabrication of advanced
films, specialty fibers, and engineering plastics. However, mainstream reinforcement …

Structure of the Thermally Induced Cross-Link in C-Linked Methyl Ester-Functionalized Polydicyclopentadiene (fPDCPD)

TJ Cuthbert, T Li, AWH Speed, JE Wulff - Macromolecules, 2018 - ACS Publications
Polydicyclopentadiene (PDCPD) is a durable, highly cross-linked material that is used
industrially for the production of automotive body panels among other applications. We …

A new echelon of precision polypentenamers: highly isotactic branching on every five carbons

S Brits, WJ Neary, G Palui, JG Kennemur - Polymer Chemistry, 2018 - pubs.rsc.org
A series of allylic substituted cyclopentene monomers with increasing steric bulk are
investigated by ring opening metathesis polymerization to understand the effects of these …

The chemistry of the carbon-transition metal double and triple bond: annual survey covering the year 2016

JW Herndon - Coordination Chemistry Reviews, 2018 - Elsevier
This is a review of papers published in the year 2016 that focus on the synthesis, reactivity,
or properties of compounds containing a carbon-transition metal double or triple bond …