This review describes the main synthetic methodologies available for the preparation of P-
stereogenic phosphines and derivatives. The literature coverage focuses in the last ten …

Since the design of chiral ligands plays a key role in the development of metal-catalysed
asymmetric reactions, many recent studies have addressed the development of novel chiral …

This review discusses methods for the asymmetric synthesis of P-chiral tri-, tetra-and
pentacoordinated organophosphorus compounds with many applications in stereoselective …

This review describes some recent developments in the area of asymmetric catalysis using
organometallic complexes of ligands which contain two or three P–O or P–N bonds. This …

Abstract A series of N, P‐ligands has been prepared, containing a chiral oxazoline ring and
as a second chiral unit a bis (N‐sulfonylamino) phosphine group embedded in a …

A series of structurally diverse diamidophosphite-sulfides were synthesized from 1, 2-
thioether alcohols. With respect to Pd (II), these hemilabile ligands showed the ability to form …

Novel P*‐monodentate diamidophosphite ligands have been prepared by a one‐step
phosphorylation of alcohols or amines. Both the electronic and the steric demands of the …

A large family of P, S-bidentate diamidophosphite ligands were readily synthesized from
accessible hydroxyl-thioether compounds. One type of Pd (II) cationic allylic complex with …

The first asymmetric synthesis of P-stereogenic 2-hydroxyarylphosphine ligands is
described, using borane complexation methodology. This synthesis is based on the highly …

Starting from inexpensive materials and following simple protocols various N-
phosphorylated sulfoximines and sulfinamides have been synthesized. The newly prepared …