Metal-mediated and metal-catalyzed reactions of isocyanides

VP Boyarskiy, NA Bokach, KV Luzyanin… - Chemical …, 2015 - ACS Publications
1. INTRODUCTION A timely subtitle to this Review focused on conversions of isocyanides at
metal centers could have been “a platinum jubilee of the first metal-mediated reaction …

1, 3-Dipolar cycloaddition of nitrone-type dipoles to uncomplexed and metal-bound substrates bearing the CN triple bond

NA Bokach, ML Kuznetsov, VY Kukushkin - Coordination Chemistry …, 2011 - Elsevier
Metal-free and metal-mediated routes for 1, 3-dipolar cycloaddition of nitrone-type dipoles to
substrates bearing the CN triple bond are compared and the reactions are categorized. In 1 …

Pd-catalyzed direct deoxygenative arylation of non-π-extended benzyl alcohols with boronic acids via transient formation of non-innocent isoureas

G Toupalas, G Thomann, L Schlemper… - ACS …, 2022 - ACS Publications
We report the direct arylation of non-derivatized alcohols with boronic acids and
demonstrate that a Pd catalyst, in combination with a carbodiimide, can be used to forge a C …

Substituent-Dependent Azide Addition to Isocyanides Generates Strongly Luminescent Iridium Complexes

C Jiang, LM Cañada, NB Nguyen… - Journal of the …, 2023 - ACS Publications
Ligand-centered functionalization reactions offer diverse strategies to prepare luminescent
organometallic compounds. These compounds can have unique structures that are not …

1-(2-Iodophenyl)-1H-tetrazole as a ligand for Pd (II) catalyzed Heck reaction

AK Gupta, CH Song, CH Oh - Tetrahedron letters, 2004 - Elsevier
1-(2-Iodophenyl)-1H-tetrazole as a ligand for Pd(II) catalyzed Heck reaction - ScienceDirect
Skip to main contentSkip to article Elsevier logo Journals & Books Search RegisterSign in …

Selective Gold‐Catalysed Synthesis of Cyanamides and 1‐Substituted 1H‐Tetrazol‐5‐Amines from Isocyanides

K Škoch, I Císařová, P Štěpnička - Chemistry–A European …, 2018 - Wiley Online Library
The newly discovered gold‐catalysed reaction of isocyanides with hydrazoic acid generated
in situ from trimethylsilyl azide and methanol (or, alternatively, from NaN3/AcOH) produces …

Theoretical study of Re (IV) and Ru (II) bis-isocyanide complexes and their reactivity in cycloaddition reactions with nitrones

AS Novikov, ML Kuznetsov - Inorganica Chimica Acta, 2012 - Elsevier
Bis-isocyanide complexes of Re (IV) and Ru (II) trans-/cis-[ReCl4 (CNMe) 2] and trans-/cis-
[RuCl2 (PH3) 2 (CNMe) 2] and their cycloaddition reactions with nitrone CH2N (Me) O were …

Theory of the Formation and Decomposition of N‐Heterocyclic Aminooxycarbenes through Metal‐Assisted [2+ 3]‐Dipolar Cycloaddition/Retro‐Cycloaddition

AS Novikov, ML Kuznetsov… - Chemistry–A European …, 2013 - Wiley Online Library
The theoretical background of the formation of N‐heterocyclic oxadiazoline carbenes
through a metal‐assisted [2+ 3]‐dipolar cycloaddition (CA) reaction of nitrones R1CH N …

Cyclometallated Pd (ii) azido complexes containing 6-phenyl-2, 2′-bipyridyl or 2-phenylpyridyl derivatives: synthesis and reactivity toward organic isocyanides and …

YJ Kim, X Chang, JT Han, MS Lim, SW Lee - Dalton Transactions, 2004 - pubs.rsc.org
Cyclometallated palladium (II) azido complexes containing C, N, N-or C, N-donor
ligands,[Pd (N3) L](HL= 6-phenyl-2, 2′-bipyridine or 2-phenylpyridyl derivatives), showed …