Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes–fast phosphorescence or TADF?

J Nitsch, F Lacemon, A Lorbach, A Eichhorn… - Chemical …, 2016 - pubs.rsc.org
This case study on a series of monomeric, dimeric and polymeric CuI chlorido NHC–picolyl
complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast …

Cu–F interactions between cationic linear N-heterocyclic carbene copper (I) pyridine complexes and their counterions greatly enhance blue luminescence efficiency

A Liske, L Wallbaum, T Hölzel, J Foller… - Inorganic …, 2019 - ACS Publications
A series of easily accessible linear N-heterocyclic carbene (NHC) copper (I) complexes,
bearing pyridine (py) and its derivatives as chromophore ligands, are barely emissive in the …

Copper-catalyzed Hiyama coupling of (hetero) aryltriethoxysilanes with (hetero) aryl iodides

SK Gurung, S Thapa, AS Vangala, R Giri - Organic letters, 2013 - ACS Publications
A CuI-catalyzed Hiyama coupling was achieved, which proceeds in the absence of an
ancillary ligand for aryl–heteroaryl and heteroaryl–heteroaryl couplings. AP, N-ligand is …

Luminescent aryl–group eleven metal complexes

JM López-de-Luzuriaga, M Monge, ME Olmos - Dalton Transactions, 2017 - pubs.rsc.org
Among the coinage metal complexes displaying luminescent properties, those bearing C-
donor aryl ligands have an increasing part in the chemistry of these metals. These types of …

Organo chalcogenone-triggered luminescent copper (I) clusters for light emitting applications

S Veerapathiran, G Muduli, A Rawat… - Inorganic …, 2024 - ACS Publications
A novel organo sulfur and selenium-controlled emission behavior in discrete copper (I)
clusters has been demonstrated for the first time. The pentanuclear [Cu5Br5 (L 1) 2](1) …

Electrochemical reduction of sulfite based on gold nanoparticles/silsesquioxane-modified electrode

JP Winiarski, MR de Barros, HA Magosso, CL Jost - Electrochimica Acta, 2017 - Elsevier
This paper reports the synthesis and characterization of the water-soluble form of 3-n-propyl
(4-methylpyridinium) silsesquioxane chloride (Si4Pic+ Cl−), which showed potential for …

Combination of argentophilic and perfluorophenyl-perfluorophenyl interactions supports a head-to-head [2+ 2] photodimerization in the solid state

MA Sinnwell, J Baltrusaitis… - Crystal Growth & …, 2015 - ACS Publications
Face-to-face perfluorophenyl–perfluorophenyl interactions (C6F5··· C6F5) are achieved in a
disilver metal–organic complex. The C6F5··· C6F5 interactions along with argentophilic …

β-diketiminate germylene-supported pentafluorophenylcopper (I) and-silver (I) complexes [LGe (Me)(CuC6F5) n] 2 (n= 1, 2), LGe [C (SiMe3) N2] AgC6F5, and {LGe [C …

N Zhao, J Zhang, Y Yang, H Zhu, Y Li, G Fu - Inorganic Chemistry, 2012 - ACS Publications
Reactions of LGeMe (L= HC [C (Me) N-2, 6-i Pr2C6H3] 2) with 0.25 or 0.5 equiv of (CuC6F5)
4 gave the products [LGe (Me) CuC6F5] 2 (1) and [LGe (Me)(CuC6F5) 2] 2 (2), respectively …

C–H activation of fluoroarenes: synthesis, structure, and luminescence properties of copper (I) and gold (I) complexes bearing 2-phenylpyridine ligands

R Molteni, K Edkins, M Haehnel, A Steffen - Organometallics, 2016 - ACS Publications
Although 2-phenylpyridine (ppy)-type complexes have been employed very successfully for
the design of luminescent IrIII and PtII complexes, corresponding d10-coinage metal …

Assembly of Heterometallic Silver (I)–Copper (I) Alkyl-1, 3-diynyl Clusters via Inner-Core Expansion

SCK Hau, MCL Yeung, VWW Yam… - Journal of the American …, 2016 - ACS Publications
New tetranuclear supramolecular precursors [(R C C C C) Ag] 4 (R= i Pr, t Bu, and
chx) are employed to construct a series of heterometallic silver (I)–copper (I) alkyl-1, 3-diynyl …