Microwave three‐wave mixing has emerged as a novel approach for studying chiral
molecules in the gas phase. This technique employs resonant microwave pulses and is a …

Chiroptical spectroscopy techniques for the differentiation of enantiomers in the condensed
phase are based on an established paradigm that relies on symmetry breaking using …

This book details chiroptical spectroscopic methods: electronic circular dichroism (ECD),
optical rotatory dispersion (ORD), vibrational circular dichroism (VCD), and vibrational …

Since its invention in 2006, the broadband chirped pulse Fourier transform spectrometer has
transformed the field of microwave spectroscopy. The technique enables the collection of …

Vibrational optical activity (VOA) consisting of infrared vibrational circular dichroism (VCD)
and vibrational Raman optical activity (ROA) was predicted, discovered, and confirmed …

Chiral discrimination that is efficient at detecting tiny amounts of chiral substances,
especially at the single-molecule level, is in great demand. Here, we propose a single-shot …

We report the experimental demonstration of coherent enantiomer‐selective enrichment of
chiral molecules by employing a novel microwave five‐pulse scheme. Our results show that …

Three-wave mixing spectroscopy of chiral molecules, which exist in left-handed and right-
handed conformations, allows for enantioselective population transfer despite random …

The absolute configuration of a molecule can be established by analysis of molecular
rotational spectra of the analyte complexed with a small chiral molecule of known …

Enantiodiscrimination with single-molecule and single-shot resolution is fundamental for the
understanding of the fate and behavior of two enantiomers in chemical reactions, biological …