Thermoresponsive interfaces obtained using poly (N-isopropylacrylamide)-based copolymer for bioseparation and tissue engineering applications

K Nagase - Advances in Colloid and Interface Science, 2021 - Elsevier
Abstract Poly (N-isopropylacrylamide)(PNIPAAm) is the most well-known and widely used
stimuli-responsive polymer in the biomedical field owing to its ability to undergo temperature …

Creation of softmaterials based on self-oscillating polymer gels

R Yoshida - Polymer Journal, 2022 - nature.com
In 1996, the author reported “self-oscillating” polymer gels that spontaneously repeat
swelling–deswelling changes in a closed solution without any on–off switching by external …

Temporally programmed polymer–solvent interactions using a chemical reaction network

B Klemm, RW Lewis, I Piergentili, R Eelkema - Nature Communications, 2022 - nature.com
Out of equilibrium operation of chemical reaction networks (CRNs) enables artificial
materials to autonomously respond to their environment by activation and deactivation of …

Recent developments in self-oscillating polymeric systems as smart materials: from polymers to bulk hydrogels

YS Kim, R Tamate, AM Akimoto, R Yoshida - Materials Horizons, 2017 - pubs.rsc.org
As novel functional materials, we developed self-oscillating polymeric materials composed
of synthetic polymers coupled with an oscillating chemical reaction, the so-called Belousov …

Anisotropically Deforming Sandwich-Type Self-Oscillating Gels: A Hierarchical Model Platform of Cardiac Tissue

WS Lee, T Enomoto, A Mizutani Akimoto… - Chemistry of …, 2024 - ACS Publications
Here, we present sandwich-type self-oscillating gels as a potential model for exploring the
cardiac hierarchy and derived emergent properties. The sandwich-type self-oscillating gels …

Harmonic resonance and entrainment of propagating chemical waves by external mechanical stimulation in BZ self-oscillating hydrogels

T Geher-Herczegh, Z Wang… - Proceedings of the …, 2024 - National Acad Sciences
Smart polymer materials that are nonliving yet exhibit complex “life-like” or biomimetic
behaviors have been the focus of intensive research over the past decades, in the quest to …

Poly (N-isopropylacrylamide) based thermoresponsive polymer brushes for bioseparation, cellular tissue fabrication, and nano actuators

K Nagase, T Okano, H Kanazawa - Nano-Structures & Nano-Objects, 2018 - Elsevier
Many thermoresponsive surfaces for biomedical applications have been developed using
various techniques for modifying substrates with thermoresponsive polymers. In addition …

Delayed mechanical response to chemical kinetics in self-oscillating hydrogels driven by the Belousov–Zhabotinsky reaction

T Geher-Herczegh, Z Wang, T Masuda… - …, 2021 - ACS Publications
We show experimentally that chemical and mechanical self-oscillations in Belousov–
Zhabotinsky hydrogels are inherently asynchronous, that is, there is a detectable delay in …

Capsule self-oscillating gels showing cell-like nonthermal membrane/shape fluctuations

WS Lee, T Enomoto, AM Akimoto, R Yoshida - Materials Horizons, 2023 - pubs.rsc.org
A primary interest in cell membrane and shape fluctuations is establishing experimental
models reflecting only nonthermal active contributions. Here we report a millimeter-scaled …

Fabrication of submillimeter-sized spherical self-oscillating gels and control of their isotropic volumetric oscillatory behaviors

WS Lee, T Enomoto, AM Akimoto, R Yoshida - Soft Matter, 2023 - pubs.rsc.org
In this study, we established a fabrication method and analyzed the volumetric self-
oscillatory behaviors of submillimeter-sized spherical self-oscillating gels. We validated that …