Naphthopyran molecular switches and their emergent mechanochemical reactivity

ME McFadden, RW Barber, AC Overholts… - Chemical Science, 2023 - pubs.rsc.org
Naphthopyran molecular switches undergo a ring-opening reaction upon external
stimulation to generate intensely colored merocyanine dyes. Their unique modularity and …

[HTML][HTML] Phenomenon to functions: Photochromism of diarylpyrans, spectrokinetic properties and functional materials

A Mukhopadhyay, JN Moorthy - Journal of Photochemistry and …, 2016 - Elsevier
Diarylbenzo-and naphthopyrans are one of the important and well-known classses of
organic photochromic systems. Their photolysis leads to highly colored o-quinonoid …

[图书][B] CRC Handbook of Organic Photochemistry and Photobiology, Volumes 1 & 2

WM Horspool, F Lenci - 2003 - taylorfrancis.com
The second edition of this best-selling handbook is bigger, more comprehensive, and now
completely current. In addition to thorough updates to the discussions featured in the first …

Helicity as a Steric Force: Stabilization and Helicity-Dependent Reversion of Colored o-Quinonoid Intermediates of Helical Chromenes

JN Moorthy, S Mandal, A Mukhopadhyay… - Journal of the …, 2013 - ACS Publications
Photolysis of regioisomeric helical chromenes 1 and 2 leads to colored reactive
intermediates. While the latter generally decay quite rapidly, they are found to be longer …

Photodecarbonylation of α-diketones: a mechanistic study of reactions leading to acenes

R Mondal, AN Okhrimenko, BK Shah… - The Journal of …, 2008 - ACS Publications
Poly (acene) s are significant compounds for various electronic applications. A clean, one-
step synthesis involves α-diketones (2− 4), which undergo facile Strating− Zwanenburg …

[HTML][HTML] Quantitative analysis of the dynamic behaviour of photochromic systems

S Delbaere, G Vermeersch, JC Micheau - Journal of Photochemistry and …, 2011 - Elsevier
The good understanding of a photochromic reaction mechanism requires the establishment
of the list of all the transient species and the definition of their connecting processes. The …

The role of temperature in the photochromic behaviour

F Ortica - Dyes and Pigments, 2012 - Elsevier
This paper reviews a series of photochromic systems belonging to the classes of
spirooxazines, chromenes and arylethenes, which have been recently investigated in our …

Dynamics of the excited states of chromenes studied by fast and ultrafast spectroscopies

PL Gentili, E Danilov, F Ortica, MAJ Rodgers… - Photochemical & …, 2004 - Springer
In this paper, the photodynamics of three chromenes (2, 2-spiro-adamantyl-7, 8-benzo (2 H)
chromene, 2, 2-diphenyl (2 H) chromene and 2, 2-diphenyl-5, 6-benzo (2 H) chromene) has …

Comprehensive modulation of naphthopyran photochromism in a rigid host matrix by applying polymer conjugation

F Ercole, TP Davis, RA Evans - Macromolecules, 2009 - ACS Publications
Naphthopyran polymer conjugates of various rigidities were synthesized by atom transfer
radical polymerization (ATRP), and their photochromic properties were tested within a rigid …

The photochemical ring opening reaction of chromene as seen by transient absorption and fluorescence spectroscopy

TT Herzog, G Ryseck, E Ploetz, T Cordes - … & Photobiological Sciences, 2013 - pubs.rsc.org
In this paper we investigate the photochromic ring-opening reaction of 2, 2-diphenyl-5, 6-
benzo (2H) chromene. In particular, we study the uncertainties and contradictions in various …