Heterogeneous catalytic approaches in C–H activation reactions

S Santoro, SI Kozhushkov, L Ackermann, L Vaccaro - Green Chemistry, 2016 - pubs.rsc.org
Despite the undisputed advances and progress in metal-catalyzed C–H functionalizations,
this atom-economical approach had thus far largely been developed with the aid of various …

Formation and stabilization of nanosized Pd particles in catalytic systems: Ionic nitrogen compounds as catalytic promoters and stabilizers of nanoparticles

VM Chernyshev, OV Khazipov, DB Eremin… - Coordination Chemistry …, 2021 - Elsevier
Actual palladium catalysts in synthetic transformations in reaction mixtures are usually
represented by dynamic catalytic systems that contain various interconvertible forms of metal …

External oxidant-free oxidative cross-coupling: a photoredox cobalt-catalyzed aromatic C–H thiolation for constructing C–S bonds

G Zhang, C Liu, H Yi, Q Meng, C Bian… - Journal of the …, 2015 - ACS Publications
An external oxidant-free oxidative coupling for aromatic C–H thiolation by visible-light
photoredox cobalt-catalysis has been developed. Various substrates could afford …

Copper-Catalyzed Direct Benzylation or Allylation of 1,3-Azoles with N-Tosylhydrazones

X Zhao, G Wu, Y Zhang, J Wang - Journal of the American …, 2011 - ACS Publications
Copper-Catalyzed Direct Benzylation or Allylation of 1,3-Azoles with N-Tosylhydrazones |
Journal of the American Chemical Society ACS ACS Publications C&EN CAS Find my institution …

Catalytic C–H bond functionalisation chemistry: the case for quasi-heterogeneous catalysis

AJ Reay, IJS Fairlamb - Chemical Communications, 2015 - pubs.rsc.org
This feature article examines the potential of heterogeneous Pd species to mediate catalytic
C–H bond functionalisation processes employing suitable substrates (eg aromatic …

C–H arylation of triphenylene, naphthalene and related arenes using Pd/C

KD Collins, R Honeker, S Vásquez-Céspedes… - Chemical …, 2015 - pubs.rsc.org
A highly selective arylation of a number of polyaromatic hydrocarbons (PAHs) with
aryliodonium salts and Pd/C as the only reagent is reported. The first C–H functionalization …

Palladium-catalyzed desulfitative C–H arylation of azoles with sodium sulfinates

R Chen, S Liu, X Liu, L Yang, GJ Deng - Organic & Biomolecular …, 2011 - pubs.rsc.org
A palladium-catalyzed desulfitative C–H arylation of azoles with sodium sulfinates using Cu
(OAc) 2· H2O as oxidant has been discovered. The reaction proceeded well for a range of …

Ligand-free CuO nanospindle catalyzed arylation of heterocycle C–H bonds

W Zhang, Q Zeng, X Zhang, Y Tian, Y Yue… - The Journal of …, 2011 - ACS Publications
CuO nanospindles have been developed to efficiently catalyze the direct arylation of
heterocycle C–H bonds with moderate to excellent yields. This reaction can be applied to …

[PDF][PDF] Transition-metal-catalyzed rearrangement of allenyl sulfides: a route to furan derivatives

L Peng, X Zhang, M Ma, J Wang - … -INTERNATIONAL EDITION IN …, 2007 - academia.edu
Allene chemistry has attracted considerable attention in recent years. In particular, the
transition-metal-catalyzed reaction of allene derivatives bearing an α substituent, such as …

CC Bond Formation via CH Activation and CN Bond Formation via Oxidative Amination Catalyzed by Palladium‐ Polyoxometalate Nanomaterials Using …

LL Chng, J Zhang, J Yang, M Amoura… - Advanced Synthesis & …, 2011 - Wiley Online Library
An efficient heterogeneous palladium‐polyoxometalate catalyst with the formula Pd‐
H6PV3Mo9O40/C has been successfully developed for carbon‐carbon (C C) bond …