Modelling of the surface tension of binary and ternary mixtures with the gradient theory of fluid interfaces

C Miqueu, B Mendiboure, C Graciaa, J Lachaise - Fluid phase equilibria, 2004 - Elsevier
The gradient theory of fluid interfaces is applied to compute the surface tension of various
binary and ternary mixtures made up of a gas (carbon dioxide, nitrogen or methane) and …

Measurement and modelling of high pressure density and interfacial tension of (gas+ n-alkane) binary mixtures

LMC Pereira, A Chapoy, R Burgass, B Tohidi - The Journal of Chemical …, 2016 - Elsevier
The deployment of more efficient and economical extraction methods and processing
facilities of oil and gas requires the accurate knowledge of the interfacial tension (IFT) of fluid …

Use of equations of state and coarse grained simulations to complement experiments: Describing the interfacial properties of carbon dioxide+ decane and carbon …

A Mejia, M Cartes, H Segura… - Journal of Chemical & …, 2014 - ACS Publications
We report surface tension measurements, coexisting densities, concentration profiles along
the interfacial region, surface activities, and relative Gibbs adsorption isotherms for binary …

Modeling of the surface tension of multicomponent mixtures with the gradient theory of fluid interfaces

C Miqueu, B Mendiboure, A Graciaa… - Industrial & engineering …, 2005 - ACS Publications
The gradient theory of fluid interfaces is for the first time applied, without any lumping, to
complex mixtures of more than three components, here made up of hydrocarbons and of a …

Interfacial tensions of industrial fluids from a molecular‐based square gradient theory

JM Garrido, A Mejía, MM Pineiro, FJ Blas… - AIChE …, 2016 - Wiley Online Library
This work reports a procedure for predicting the interfacial tension (IFT) of pure fluids. It is
based on scaling arguments applied to the influence parameter of the van der Waals theory …

Interfacial properties of selected binary mixtures containing n-alkanes

EA Müller, A Mejía - Fluid Phase Equilibria, 2009 - Elsevier
We report the correlation and prediction of the subcritical vapour–liquid interfacial properties
of three asymmetric binary mixtures composed of long n-alkanes in equilibria with a smaller …

Interfacial Properties of Water/CO2: A Comprehensive Description through a Gradient Theory−SAFT-VR Mie Approach

T Lafitte, B Mendiboure, MM Pineiro… - The Journal of …, 2010 - ACS Publications
The Gradient Theory of fluid interfaces is for the first time combined with the SAFT-VR Mie
EOS to model the interfacial properties of the water/CO2 mixture. As a preliminary test of the …

Calculation of the interfacial tension of the methane–water system with the linear gradient theory

KAG Schmidt, GK Folas, B Kvamme - Fluid Phase Equilibria, 2007 - Elsevier
The linear gradient theory (LGT) combined with the Soave–Redlich–Kwong (SRK EoS) and
the Peng–Robinson (PR EoS) equations of state has been used to correlate the interfacial …

Comprehensive Characterization of Interfacial Behavior for the Mixture CO2 + H2O + CH4: Comparison between Atomistic and Coarse Grained Molecular …

JM Miguez, JM Garrido, FJ Blas, H Segura… - The Journal of …, 2014 - ACS Publications
The accurate description of the phase equilibria and interfacial behavior of the ternary
mixture H2O+ CO2+ CH4 is of fundamental importance in processes related with enhanced …

Surface tension of chain molecules through a combination of the gradient theory with the CPA EoS

MB Oliveira, IM Marrucho, JAP Coutinho… - Fluid Phase …, 2008 - Elsevier
Despite the interest in systems containing non-associating compounds such as alkanes and
fluoroalkanes or associating compounds like alkanols, their vapor–liquid interfaces have …