From molecular to supramolecular electronics

H Chen, J Fraser Stoddart - Nature Reviews Materials, 2021 - nature.com
Using individual molecules as conducting bridges for electrons offers opportunities when
investigating quantum phenomena that are not readily accessible from experiments …

Molecular electronics: creating and bridging molecular junctions and promoting its commercialization

T Li, VK Bandari, OG Schmidt - Advanced Materials, 2023 - Wiley Online Library
Molecular electronics is driven by the dream of expanding Moore's law to the molecular level
for next‐generation electronics through incorporating individual or ensemble molecules into …

Spinterface origin for the chirality-induced spin-selectivity effect

S Alwan, Y Dubi - Journal of the American Chemical Society, 2021 - ACS Publications
When electrons are injected through a chiral molecule, the resulting current may become
spin polarized. This effect, known as the chirality-induced spin-selectivity (CISS) effect, has …

Chiral-induced spin selectivity and non-equilibrium spin accumulation in molecules and interfaces: A first-principles study

S Naskar, V Mujica, C Herrmann - The Journal of Physical …, 2023 - ACS Publications
Electrons moving through chiral molecules are selected according to their spin orientation
and the helicity of the molecule, an effect known as chiral-induced spin selectivity (CISS) …

Exchange-induced spin polarization in a single magnetic molecule junction

T Pei, JO Thomas, S Sopp, MY Tsang, N Dotti… - Nature …, 2022 - nature.com
Many spintronic devices rely on the presence of spin-polarized currents at zero magnetic
field. This is often obtained by spin exchange-bias, where an element with long-range …

Synthesis and characterization of a formal 21-electron cobaltocene derivative

S Takebayashi, J Ariai, U Gellrich, SV Kartashov… - Nature …, 2023 - nature.com
Metallocenes are highly versatile organometallic compounds. The versatility of the
metallocenes stems from their ability to stabilize a wide range of formal electron counts. To …

Mechanically tunable quantum interference in ferrocene-based single-molecule junctions

M Camarasa-Gómez, D Hernangómez-Pérez… - Nano Letters, 2020 - ACS Publications
Ferrocenes are ubiquitous organometallic building blocks that comprise a Fe atom
sandwiched between two cyclopentadienyl (Cp) rings that rotate freely at room temperature …

Hard–soft chemistry design principles for predictive assembly of single molecule-metal junctions

HE Skipper, CV May, AL Rheingold… - Journal of the …, 2021 - ACS Publications
The achievement of atomic control over the organic–inorganic interface is key to
engineering electronic and spintronic properties of molecular devices. We leverage insights …

Formation and evolution of metallocene single-molecule circuits with direct gold-π links

B Lawson, P Zahl, MS Hybertsen… - Journal of the American …, 2022 - ACS Publications
Single-molecule circuits with group 8 metallocenes are formed without additional linker
groups in scanning tunneling microscope-based break junction (STMBJ) measurements at …

Magnetic, mechanically interlocked porphyrin–carbon nanotubes for quantum computation and spintronics

S Moreno-Da Silva, JI Martínez… - Journal of the …, 2021 - ACS Publications
Atomic-scale reproducibility and tunability endorse magnetic molecules as candidates for
spin qubits and spintronics. A major challenge is to implant those molecular spins into circuit …