Conspectus In spite of the importance of energetic materials to a broad range of military
(munitions, missiles) and civilian (mining, space exploration) technologies, the introduction …

This Article revisits the “Definition of the Halogen Bond (IUPAC Recommendations
2013)”[Desiraju, GR Pure Appl. Chem. 2013, 85 (8), 1711–1713], recommendations that fail …

Halogen bonds are currently new noncovalent interactions due to their moderate strength
and high directionality, which are widely investigated in crystal engineering. The study about …

The nitrosoguanidinate complex [Ni {NH C (NMe2) NN (O)} 2](1) was cocrystallized with I2
and sym-trifluorotriiodobenzene (FIB) to give associates 1· 2I2 and 1· 2FIB. Structures of …

Carbon, although the central element in organic chemistry, has been traditionally neglected
as a target for directional supramolecular interactions. The design of supramolecular …

Supramolecular synthesis, a field of study in chemistry, offers a versatile approach to
construct complex structures using non-covalent interactions. In this study, we explore the …

The complexes [MII (acac) 2](M= Cu 1, Pd 2, Pt 3; Hacac= acetylacetone) and 1, 4-
diiodotetrafluorobenzene (FIB) were cocrystallized in CHCl3–MeOH solutions to form …

Diversity of mutual orientations of Y–S and I–X and covalent bonds in molecular crystals
complicate categorizing noncovalent chalcogen and halogen bonds. Here, the different …

In this work, a detailed Hammett structure–structure correlation was applied to a range of
chalcogen-bonded co-crystals prepared by combining 4′-substituted derivatives of the …

Halogen‐bond donors (halogen‐based Lewis acids) have now found various applications in
diverse fields of chemistry. The goal of this study was to identify a parameter obtainable from …