[HTML][HTML] Photoswitchable dynamic conjugate addition-elimination reactions as a tool for light-mediated click and clip chemistry

H Lu, H Ye, M Zhang, Z Liu, H Zou, L You - Nature Communications, 2023 - nature.com
Phototriggered click and clip reactions can endow chemical processes with high
spatiotemporal resolution and sustainability, but are challenging with a limited scope. Herein …

Thickness Gradient in Polymer Coating by Reactive Layer-by-Layer Assembly on Solid Substrate

S Ozenler, AA Alkan, US Gunay, O Daglar… - ACS …, 2023 - ACS Publications
The study describes a simple yet robust methodology for forming gradients in polymer
coatings with nanometer-thickness precision. The thickness gradients of 0–20 nm in the …

Amino-yne reaction: An exquisite method for polymer-polymer conjugation and post-polymerization modification

E Akar, S Luleburgaz, US Gunay, V Kumbaraci… - European Polymer …, 2023 - Elsevier
The amino-yne reaction, which performs between an electron-deficient alkyne and an
amine, has been shown to proceed with high efficiency under mild conditions and has …

Propiolated castor oil: a novel and highly versatile bio-based platform for extremely fast, catalyst-, and solvent-free amino-yne click reactions

B Celik, D Kandemir, S Luleburgaz… - ACS Sustainable …, 2023 - ACS Publications
The quest for sustainable monomers and “green” synthetic pathways for the design,
fabrication, and modification of various polymers is of great importance and attracts a great …

Ultrafast synthesis of dialkyne-functionalized polythioether and post-polymerization modification via click chemistry

B Pektas, G Sagdic, O Daglar, S Luleburgaz, US Gunay… - Polymer, 2022 - Elsevier
Herein, we prepare a polythioether with double “clickable” alkyne groups in each repeating
unit via an extremely rapid polymerization method and combine it with Cu (I)-catalyzed azide …

Preparation of poly (oxanorbornene) based single and double-folding polymers via nucleophilic aromatic substitution reaction

B Alkan, BA Temel, H Durmaz, G Temel - European Polymer Journal, 2024 - Elsevier
A facile approach is introduced to prepare single-chain nanoparticles (SCNPs) utilizing
intramolecular crosslinking based on nucleophilic aromatic substitution reaction. The linear …

Post-polymerization modification of pentafluorophenyl-functionalized polythioether via thiol-para-fluoro click reaction

G Sagdic, US Gunay - Journal of Macromolecular Science, Part A, 2023 - Taylor & Francis
In this work, a rapid polymerization method was combined with thiol-para-fluoro (TPF)“click”
post-polymerization modification (PPM) strategy. To this end, a reactive monomer, namely …

Development of Jeffamine cross-linked poly (vinyl chloride) films by sequential CuAAC click chemistry and aza-Michael addition

C Altinkok - Journal of Macromolecular Science, Part A, 2023 - Taylor & Francis
The objective of this study is to present a promising route to design a series of new poly
(vinyl chloride)(PVC) films cross-linked with polyetheramine (PEA), namely jeffamine, by …

Imide-Yne Click Polymerization: A New and Versatile Tool for the Toolbox of X-Yne Click Polymerization

O Aslanturk, G Sagdic, E Cakmakci, H Durmaz… - Polymer …, 2024 - pubs.rsc.org
The Michael reaction, a cornerstone in organic chemistry, continues to revolutionize the field
with its unparalleled versatility in forming carbon-carbon, carbon-oxygen, carbon-nitrogen …

Facile Modification of Propiolated Castor Oil via Nucleophilic Thiol‐Yne Click Reactions

D KALAYCI, E AKAR, S LULEBURGAZ… - … Chemistry and Physics - Wiley Online Library
The combination of modern click protocols and bio‐based building blocks is a great step
towards energy‐efficient, sustainable, and tailorable polymer production. Herein, we chose …