Green synthesis of reticular materials
To help ensure a prosperous future on Earth for coming generations, academia and industry
need to transform the way they plan and carry out the synthesis of novel materials to make …
need to transform the way they plan and carry out the synthesis of novel materials to make …
Characterization, Structure, and Reactivity of Hydroxyl Groups on Metal‐Oxide Cluster Nodes of Metal–Organic Frameworks: Structural Diversity and Keys to …
Among the most stable metal–organic frameworks (MOFs) are those incorporating nodes
that are metal oxide clusters with frames such as Zr6O8. This review is a summary of the …
that are metal oxide clusters with frames such as Zr6O8. This review is a summary of the …
Bioinspired Proton Pump on Ferroelectric HfO2-Coupled Ir Catalysts with Bidirectional Hydrogen Spillover for pH-Universal and Superior Hydrogen Production
The improvement of hydrogen evolution reaction kinetics can be largely accelerated by
introducing a well-designed hydrogen spillover pathway into the catalysts. However, the …
introducing a well-designed hydrogen spillover pathway into the catalysts. However, the …
A family of dual-anion-based sodium superionic conductors for all-solid-state sodium-ion batteries
The sodium (Na) superionic conductor is a key component that could revolutionize the
energy density and safety of conventional Na-ion batteries. However, existing Na superionic …
energy density and safety of conventional Na-ion batteries. However, existing Na superionic …
Cooperative photocatalysis of hafnium-based metal–organic framework and TEMPO for selective oxidation of sulfides
B Zeng, W Sheng, F Huang, K Zhang, K Xiong… - Chemical Engineering …, 2023 - Elsevier
Metal–organic frameworks (MOFs) have been exploited through their metal–oxo clusters
and organic ligands toward promising photocatalysis. In this work, a hafnium (Hf)-based …
and organic ligands toward promising photocatalysis. In this work, a hafnium (Hf)-based …
Influence of Water Content on Speciation and Phase Formation in Zr–Porphyrin‐Based MOFs
Controlled synthesis of phase‐pure metal–organic frameworks (MOFs) is essential for their
application in technological areas such as catalysis or gas sorption. Yet, knowledge of their …
application in technological areas such as catalysis or gas sorption. Yet, knowledge of their …
How reproducible is the synthesis of Zr–porphyrin metal–organic frameworks? An interlaboratory study
Metal–organic frameworks (MOFs) are a rapidly growing class of materials that offer great
promise in various applications. However, the synthesis remains challenging: for example, a …
promise in various applications. However, the synthesis remains challenging: for example, a …
Exploring porous structures without crystals: advancements with pair distribution function in metal-and covalent organic frameworks
The pair distribution function (PDF) is a versatile characterisation tool in materials science,
capable of retrieving atom–atom distances on a continuous scale (from a few angstroms to …
capable of retrieving atom–atom distances on a continuous scale (from a few angstroms to …
Fundamental perspectives on the electrochemical water applications of metal–organic frameworks
X He - Nano-Micro Letters, 2023 - Springer
Highlights The recent development and implementation of metal–organic frameworks
(MOFs) and MOF-based materials in electrochemical water applications are reviewed. The …
(MOFs) and MOF-based materials in electrochemical water applications are reviewed. The …
Fatty acid capped, metal oxo clusters as the smallest conceivable nanocrystal prototypes
D Van den Eynden, R Pokratath, JP Mathew… - Chemical …, 2023 - pubs.rsc.org
Metal oxo clusters of the type M6O4 (OH) 4 (OOCR) 12 (M= Zr or Hf) are valuable building
blocks for materials science. Here, we synthesize a series of zirconium and hafnium oxo …
blocks for materials science. Here, we synthesize a series of zirconium and hafnium oxo …