Transition metal (TM)‐catalyzed difunctionalization of unactivated olefins with two carbon‐
based entities is a powerful method to construct complex molecular architectures rapidly …

As a straightforward strategy for rapidly increasing molecular complexity,
dicarbofunctionalization of alkenes has attracted substantial interests of organic synthesis …

The use of combined Heck carbometalation and cross-coupling remains one of the most
powerful ways for the difunctionalization of unactivated olefins with organometallic reagents …

We disclose a strategy for Ni-catalyzed dicarbofunctionalization of olefins in styrenes by
intercepting Heck C (sp3)–NiX intermediates with arylzinc reagents. This approach utilizes a …

We report a Ni-catalysed diarylation of unactivated olefins in dimethylpyridylvinylsilane by
intercepting Heck C (sp3)–NiX intermediates, derived from aryl halides, with arylzinc …

We present a strategy that difunctionalizes unactivated olefins in 1, 2-positions with two
carbon-based entities. This method utilizes alkyl/arylzinc reagents derived from olefin …

We disclose a (terpy) NiBr2-catalyzed reaction protocol that regioselectively difunctionalizes
unactivated olefins with tethered alkyl halides and arylzinc reagents. The reaction shows an …

Transition-metal-catalyzed cross-coupling of organohalides, ethers, sulfides, amines, and
alcohols (and derivatives thereof) with Grignard reagents, known as the Kumada–Tamao …

Reported herein is a well-defined geometry-constrained tridentate N, N, O-nickel complex
for selective α-alkylation of unactivated amides using readily available alcohols as the …

diazaphospholenes hydrides (DAP‐Hs) are highly nucleophilic organic hydrides serving as
main‐group catalysts for a range of attractive transformations. DAP hydrides can act as …