Technological innovations in photochemistry for organic synthesis: flow chemistry, high-throughput experimentation, scale-up, and photoelectrochemistry

L Buglioni, F Raymenants, A Slattery… - Chemical …, 2021 - ACS Publications
Photoinduced chemical transformations have received in recent years a tremendous amount
of attention, providing a plethora of opportunities to synthetic organic chemists. However …

Naphthalenediimide and perylenediimide based donor-acceptor crystalline hybrid materials: Structures and applications

Z Liu, X Li, W Dai, JJ Liu, MJ Lin - Coordination Chemistry Reviews, 2025 - Elsevier
Donor-acceptor crystalline hybrid materials are a new type of photoactive hybrid complex
composed of two semiconductor components at the molecular level. Naphthalenediimide …

Synthetic methods driven by the photoactivity of electron donor–acceptor complexes

GEM Crisenza, D Mazzarella… - Journal of the American …, 2020 - ACS Publications
The association of an electron-rich substrate with an electron-accepting molecule can
generate a new molecular aggregate in the ground state, called an electron donor–acceptor …

[HTML][HTML] Synthetic reactions driven by electron-donor–acceptor (EDA) complexes

Z Yang, Y Liu, K Cao, X Zhang… - Beilstein Journal of …, 2021 - beilstein-journals.org
The reversible, weak ground-state aggregate formed by dipole–dipole interactions between
an electron donor and an electron acceptor is referred to as an electron-donor–acceptor …

Carbon dots as nano-organocatalysts for synthetic applications

C Rosso, G Filippini, M Prato - ACS Catalysis, 2020 - ACS Publications
Over the last decades, organic chemistry has taken a resolute step toward green catalytic
synthesis. This tries to ensure efficient and sustainable base chemical production, while also …

Shining light on halogen-bonding complexes: a catalyst-free activation mode of carbon–halogen bonds for the generation of carbon-centered radicals

HF Piedra, C Valdés, M Plaza - Chemical Science, 2023 - pubs.rsc.org
The discovery of new activation modes for the creation of carbon-centered radicals is a task
of great interest in organic chemistry. Classical activation modes for the generation of highly …

Radical perfluoroalkylation of aliphatic substrates

DE Yerien, S Barata-Vallejo, A Postigo - ACS Catalysis, 2023 - ACS Publications
A selection of perfluoroalkylation reactions of aliphatic substrates that display
methodological and synthetic amplitude will be studied, giving examples of their …

[HTML][HTML] Recent advances toward sustainable flow photochemistry

JD Williams, CO Kappe - Current Opinion in Green and Sustainable …, 2020 - Elsevier
Although flow photochemistry has significant potential in advancing sustainable processing,
there are substantial hurdles to attaining this. Development in three key areas over the past …

Metal‐Free Visible‐Light Promoted Radical Cyclization to Access Perfluoroalkyl‐Substituted Benzimidazo [2, 1‐a] isoquinolin‐6 (5H)‐ones and Indolo [2, 1‐a] …

FL Zeng, K Sun, XL Chen, XY Yuan… - Advanced Synthesis …, 2019 - Wiley Online Library
A metal‐free visible‐light‐induced cyclization procedure was developed for the rapid
synthesis of perfluoroalkyl‐substituted benzimidazo [2, 1‐a] isoquinolin‐6 (5H)‐ones and …

An oscillatory plug flow photoreactor facilitates semi-heterogeneous dual nickel/carbon nitride photocatalytic C–N couplings

C Rosso, S Gisbertz, JD Williams… - Reaction chemistry & …, 2020 - pubs.rsc.org
Carbon nitride materials have emerged as an efficient and sustainable class of
heterogeneous photocatalysts, particularly when paired with nickel in dual catalytic cross …