Conspectus In organic synthesis, ligand-modified copper (I) hydride (CuH) complexes have
become well-known reagents and catalysts for selective reduction, particularly toward …

Conspectus The oxindole scaffold is a privileged structural motif that is found in a variety of
bioactive targets and natural products. Moreover, derivatives of the oxindole structure are …

Carbon dioxide (CO2) is an important C1 source for the generation of important carboxylic
acids and derivatives. Stoichiometric and catalytic carboxylation of nucleophiles, including …

The catalytic conversion of chemical feedstocks into products of medicinal and agricultural
value is a key theme across modern synthetic chemistry. As 1, 3-dienes are readily available …

Ketone–olefin coupling reactions are common methods for the formation of carbon–carbon
bonds. This reaction class typically requires stoichiometric or super stoichiometric quantities …

Simple feedstock organic molecules, especially alkenes, are attractive starting materials in
organic synthesis because of their wide availability. Direct utilization of such bulk, inert …

Atom-efficient processes that occur via addition, redistribution, or removal of hydrogen
underlie many large-volume industrial processes and pervade all segments of chemical …

Reductive carboxylation of organo (pseudo) halides with CO2 is a powerful method to
provide carboxylic acids quickly. Notably, the catalytic reductive carbo‐carboxylation of …

Construction of new carbon–carbon bonds is the cornerstone of organic chemistry.
Organometallic reagents are amongst the most robust and versatile nucleophiles for this …

The first deoxygenative Heck reactions are described, as illustrated by formate-mediated
cine-substitutions of vinyl triflates with aryl iodides. The collective data corroborate a …