Telechelic polymers by living and controlled/living polymerization methods
Telechelic polymers, defined as macromolecules that contain two reactive end groups, are
used as cross-linkers, chain extenders, and important building blocks for various …
used as cross-linkers, chain extenders, and important building blocks for various …
[HTML][HTML] Radical-promoted single-unit monomer insertion (SUMI)[aka. reversible-deactivation radical addition (RDRA)]
We survey progress in the development of the processes for radical-promoted single-unit
monomer insertion (SUMI) or reversible deactivation radical addition (RDRA), focussing on …
monomer insertion (SUMI) or reversible deactivation radical addition (RDRA), focussing on …
RAFT agent design and synthesis
This Perspective reviews the design and synthesis of RAFT agents. First, we briefly detail the
basic design features that should be considered when selecting a RAFT agent or macro …
basic design features that should be considered when selecting a RAFT agent or macro …
Living radical polymerization by the RAFT process–a second update
This paper provides a second update to the review of reversible deactivation radical
polymerization achieved with thiocarbonylthio compounds (ZC (= S) SR) by a mechanism of …
polymerization achieved with thiocarbonylthio compounds (ZC (= S) SR) by a mechanism of …
Photoinduced Electron Transfer–Reversible Addition–Fragmentation Chain Transfer (PET-RAFT) Polymerization of Vinyl Acetate and N-Vinylpyrrolidinone: Kinetic …
Photoinduced electron transfer–reversible addition–fragmentation chain transfer (PET-
RAFT) polymerization was employed for the polymerization of unconjugated monomers …
RAFT) polymerization was employed for the polymerization of unconjugated monomers …
Ubiquitous Nature of Rate Retardation in Reversible Addition–Fragmentation Chain Transfer Polymerization
KGE Bradford, LM Petit, R Whitfield… - Journal of the …, 2021 - ACS Publications
Reversible addition–fragmentation chain transfer (RAFT) polymerization is one of the most
powerful reversible deactivation radical polymerization (RDRP) processes. Rate retardation …
powerful reversible deactivation radical polymerization (RDRP) processes. Rate retardation …
Mechanism and Kinetics of Dithiobenzoate‐Mediated RAFT Polymerization–Status of the Dilemma
G Moad - Macromolecular Chemistry and Physics, 2014 - Wiley Online Library
Dithiobenzoates are among the most popular agents for reversible addition‐fragmentation
chain transfer (RAFT) polymerization. This is attributed to the better control over molecular …
chain transfer (RAFT) polymerization. This is attributed to the better control over molecular …
RAFT Polymerization of N-Vinylimidazolium Salts and Synthesis of Thermoresponsive Ionic Liquid Block Copolymers
H Mori, M Yahagi, T Endo - Macromolecules, 2009 - ACS Publications
The polymerizations of N-vinylimidazolium salts, 1-(3-phenylpropyl)-3-vinylimidazolium
bromide (PVI-Br), 1-(6-ethoxycarbonylhexyl)-3-vinylimidazolium bromide (EHVI-Br), and 1-(2 …
bromide (PVI-Br), 1-(6-ethoxycarbonylhexyl)-3-vinylimidazolium bromide (EHVI-Br), and 1-(2 …
Step-growth polymerization by the RAFT process
Reversible Addition-Fragmentation Chain Transfer (RAFT) step-growth polymerization is an
emerging method that synergistically combines the benefits of RAFT polymerization …
emerging method that synergistically combines the benefits of RAFT polymerization …
Investigation into the photolytic stability of RAFT agents and the implications for photopolymerization reactions
The photolytic stability of various RAFT agents (ie, thiocarbonylthio-containing compounds)
under irradiation from a blue LED light source has been investigated. The effect and …
under irradiation from a blue LED light source has been investigated. The effect and …