Activation of small molecules by molecular uranium complexes

HS La Pierre, K Meyer - Progress in Inorganic Chemistry …, 2014 - Wiley Online Library
This chapter reviews the reaction chemistry of uranium complexes with small molecules of
industrial and biological importance. Specifically, carbon monoxide (CO), nitrogen monoxide …

Recent progress in the chemistry of metal amidinates and guanidinates: syntheses, catalysis and materials

FT Edelmann - Advances in organometallic chemistry, 2013 - Elsevier
This review provides a comprehensive overview of the most recent progress in chemistry
and applications of metal complexes containing heteroallylic ligands such as amidinates …

Recent advances in organoactinide chemistry as exemplified by cyclopentadienyl compounds

M Ephritikhine - Organometallics, 2013 - ACS Publications
The ubiquity of the cyclopentadienyl ligand permits us to use its complexes as
representative examples for the description of recent highlights in organometallic and more …

Hybrid amidinates and guanidinates of main group metals

T Chlupatý, A Růžička - Coordination Chemistry Reviews, 2016 - Elsevier
Complexes of main group metals containing amidinate and guanidinate ligands with an
additional functional/donor group are reviewed. Amino-, imino-, amido-, alkoxy-, phenoxy …

Functionalization of carbon dioxide and carbon disulfide using a stable uranium (III) alkyl complex

EM Matson, WP Forrest, PE Fanwick… - Journal of the American …, 2011 - ACS Publications
A rare uranium (III) alkyl complex, Tp* 2U (CH2Ph)(2)(Tp*= hydrotris (3, 5-dimethylpyrazolyl)
borate), was synthesized by salt metathesis from Tp* 2UI (1) and KCH2Ph and fully …

Importance of Energy Level Matching for Bonding in Th3+-Am3+ Actinide Metallocene Amidinates, (C5Me5)2[iPrNC(Me)NiPr]An

JR Walensky, RL Martin, JW Ziller… - Inorganic chemistry, 2010 - ACS Publications
The synthesis of a rare trivalent Th3+ complex,(C5Me5) 2 [iPrNC (Me) NiPr] Th, initiated a
density functional theory analysis on the electronic and molecular structures of trivalent …

Actinide‐Mediated Catalytic Addition of E H Bonds (E= N, P, S) to Carbodiimides, Isocyanates, and Isothiocyanates

ISR Karmel, M Tamm, MS Eisen - … Chemie International Edition, 2015 - Wiley Online Library
Unprecedented catalytic reactivity of actinide coordination complexes toward
heterocumulenes, such as carbodiimides, isocyanates, and isothiocyanates is reported. The …

Mono (imidazolin-2-iminato) actinide complexes: synthesis and application in the catalytic dimerization of aldehydes

ISR Karmel, N Fridman, M Tamm… - Journal of the American …, 2014 - ACS Publications
The synthesis of the mono (imidazolin-2-iminato) actinide (IV) complexes [(ImRN) An (N
{SiMe3) 2} 3](3–8) was accomplished by the protonolysis reaction between the respective …

Uranium-mediated carbon dioxide activation and functionalization

OP Lam, K Meyer - Polyhedron, 2012 - Elsevier
The importance of CO2 activation and functionalization is undeniable, given the surge of
effort in this area in the last few decades. Uranium complexes have begun to emerge as …

Molecular actinide compounds with soft chalcogen ligands

M Ephritikhine - Coordination Chemistry Reviews, 2016 - Elsevier
Molecular actinide compounds with soft chalcogen ligands - ScienceDirect Skip to main
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