The electronic structure, spectroscopic features, and (catalytic) reactivity of complexes with
nitrogen‐centered radical ligands are described. Complexes with aminyl ([M (. NR2)]) …

In this review, the coordination chemistry of electron‐rich metal complexes with the simple
aliphatic, anionic diphosphanylamido ligand {N (CH2CH2PR2) 2}–is covered and compared …

Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …

Abstract′ N′ front and center: The facile construction of C N bonds by the generation of
nitrogen‐centred radicals from N‐fluorobenzenesulfonimide results in the aminative …

The geometric and electronic structure of an oxidized Cu complex ([Cu Sal]+; Sal= N, N′-
bis (3, 5-di-tert-butylsalicylidene)-1, 2-cyclohexane-(1 R, 2 R)-diamine) with a non-innocent …

Electron-rich phenols, including α-rac-tocopherol Ar 1 OH, 2, 4, 6,-tri-tert-butylphenol Ar 3
OH, and butylated hydroxy-toluene Ar 4 OH, are effective electrochemical mediators for the …

The geometric and electronic structures of a series of one-electron oxidized group 10 metal
salens (Ni, Pd, Pt) have been investigated in solution and in the solid state. Ni (1) and Pd (2) …

Abstract The TeII/TeIII‐catalyzed dehydrogenative C− H phenothiazination of challenging
phenols featuring electron‐withdrawing substituents under mild aerobic conditions and with …

Nickel (Ni (Sal CF3)) and copper (Cu (Sal CF3)) complexes of an electron-poor salen ligand
were prepared, and their one-electron oxidized counterparts were studied using an array of …

The syntheses of meridionally ligated tricarbonyl complexes (PNP) Mn (CO) 3 and (PNP) Re
(CO) 3 are described (PNP=[2-P (CHMe2) 2-4-MeC6H3] 2N−). Cyclic voltammograms show …